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pro vyhledávání: '"Spirane ligands"'
We report the synthesis and the structure determination of tris -(4,5-diazo- spiro -bifluorene)ruthenium(II) chloride, a chiral building block whose racemic mixture solution spontaneously resolves and forms two crystalline, enantiomerically pure, por
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::904f7bddaebc160a13c4ec369bdb5756
https://www.bib.irb.hr/381456
https://www.bib.irb.hr/381456
Publikováno v:
Inorganica Chimica Acta. Dec2004, Vol. 357 Issue 15, p4610-4613. 4p.
Publikováno v:
Journal of Organometallic Chemistry. Jun2006, Vol. 691 Issue 13, p3089-3097. 9p.
Publikováno v:
Journal of Organometallic Chemistry. 691:3089-3097
Synthesis of rigid ansa-zirconocene precatalyst systems with a C2-bridge embedded in a spirane scaffold is described. Fulvenes were key intermediates in regio- and stereoselective preparation of the appropriate spirane ligands. Substitution in the cy