Zobrazeno 1 - 2
of 2
pro vyhledávání: '"Spencer J. Léger"'
Publikováno v:
Frontiers in Chemistry, Vol 8 (2020)
We present a contemporary mechanistic description of the light-driven conversion of cyclopropenone containing enediyne (CPE) precusors to ring-opened species amenable to further Bergman cyclization and formation of stable biradical species that have
Externí odkaz:
https://doaj.org/article/42917b01678b46c3bf92d63368e00e00
Autor:
Julia C. McCoy, Spencer J. Léger, Conrad F. Frey, Michael F. Vansco, Barbara Marchetti, Tolga N. V. Karsili
Publikováno v:
The Journal of Physical Chemistry A. 126:485-496
Criegee intermediates are important atmospheric oxidants, formed via the reaction of ozone with volatile alkenes emitted into the troposphere. Small Criegee intermediates (e.g., CH