Zobrazeno 1 - 10
of 42
pro vyhledávání: '"Sourav Kumar Santra"'
Publikováno v:
Angewandte Chemie International Edition. 59:15171-15175
Herein we report on the umpolung of Morita-Baylis-Hillman type intermediates and application to the α-functionalization of enone C-H bonds. This reaction gives direct access to α-chloro-enones, 1,2-diketones and α-tosyloxy-enones. The latter are i
Publikováno v:
Organic Letters. 22:768-771
Vinyl azides react with boron trifluoride activated Koser's hypervalent iodine reagent to afford azido-enolonium species. These previously unknown azido-enolonium species react efficiently with aromatic compounds, allyltrimethylsilane, and azoles und
Autor:
Alex M. Szpilman, Sourav Kumar Santra
Publikováno v:
The Journal of organic chemistry. 86(1)
We report a visible-light-mediated benzylic C-H oxygenation reaction. The reaction is initiated by solar light or the blue LED activation of 9,10-dibromoanthracene in a reaction with oxygen and takes place at ambient temperature and air pressure. Sec
Autor:
Abhaya Kumar Mishra, Jonatan Rahamim, Sourav Kumar Santra, Galit Parvari, Yoav Eichen, Ortal Dorfman, Andrii Bazylevich, Alex M. Szpilman
Publikováno v:
Angewandte Chemie International Edition. 60:12146-12146
Autor:
Galit Parvari, Jonatan Rahamim, Abhaya Kumar Mishra, Alex M. Szpilman, Sourav Kumar Santra, Yoav Eichen, Ortal Dorfman, Andrii Bazylevich
Publikováno v:
Angewandte Chemie. 133:12254-12254
Publikováno v:
Advanced Synthesis & Catalysis. 358:3471-3476
An iron(III)-catalyzed C-3 functionalization of flavones has been achieved using tert-butyl peroxybenzoate (TBPB)/potassium persulphate (K2S2O8) oxidant combinations with a suitable solvent. In the presence of iron(III)/tert-butyl peroxybenzoate/pota
Publikováno v:
Advanced Synthesis & Catalysis. 358:2047-2052
An unprecedented palladium(II)-catalyzed biomimetic aliphatic acyl (-COR) group transfer was observed from acyl-α-peroxycoumarins to the ortho CH sites of directing arenes. Here, the CH activation is associated with a concomitant acyl group transfer
Publikováno v:
Organic Letters. 17:5678-5681
Ruthenium(II) catalyzed oxidative C-H/O-H annulations have been demonstrated using two different directing arenes viz. 2-arylquinolinone and 2-arylbenzoxazinone with internal alkynes. Regiospecific annulations have been observed for both directing ar
Publikováno v:
European Journal of Organic Chemistry. 2015:1309-1313
An elegant synthesis of carboxylic acid anhydrides has been developed directly from arylaldehydes using CuO nanoparticles as the catalyst and tert-butyl hydroperoxide (TBHP) as the oxidant. During anhydride formation the reaction proceeds through a d
Publikováno v:
RSC Advances. 5:11960-11965
A palladium catalysed ortho-halogenation strategy has been developed using benzothiazoles and quinoxalines as the directing substrates. This method provides mono-o-halogenated product at the other available ortho site of a mono-ortho substituted 2-ar