Zobrazeno 1 - 4
of 4
pro vyhledávání: '"Soumya Sreehari"'
Autor:
Soumya Sreehari, Rudy L. Luck
Publikováno v:
Journal of Cluster Science. 21:525-541
Reaction of bis(acetylacetonato)dioxomolybdenum(VI) (MoO2(acac)2) with benzoic acid, in ethanol, yielded an oxo, ethoxide and benzoate-bridged dinuclear Mo(V) species Mo2O2(acac)2(μ-O)(μ-OC2H5)(μ-OOCC6H5) (1), with two terminal “MoO” units and
Publikováno v:
Inorganica Chimica Acta. 363:1818-1822
Reaction of the ligands diphenylphosphinylacetic acid Ph2P(O)CH2COOH (1) and 2-(tert-butylthio)phenyldiphenylphosphine oxide Ph2P(O)C6H4tBuS (2) with “MoO2Cl2”, resulted in two complexes MoO2Cl2Ph2P(O)CH2COOH (3) and MoO2Cl2Ph2P(O)C6H4tBuS(O) (4)
Publikováno v:
Journal of Cluster Science. 19:181-195
Reacting MoO2(acac)2 with Ph2POOH or Me2POOH in EtOH results in the formation of the tetranuclear molybdenum (V) clusters Mo4(μ 3-O)4(μ-O2PR2)4O4, PR2 = PPh2, 1, or PMe2, 2, in functional yields (>90% and 55% respectively). The reaction of WO2(acac
Publikováno v:
Journal of Cluster Science; Mar2008, Vol. 19 Issue 1, p181-195, 15p