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Syntheses and Redox Properties of Carboxylate-Ligated Hexanuclear Ce(IV) Clusters and Their Photoinduced Homolysis of the Ce(IV)–Ligand Covalent Bond

Autor: Tomomi Kawakami, Sota Tamaki, Satoru Shirase, Hayato Tsurugi, Kazushi Mashima

Publikováno v: Inorganic Chemistry. 61:20461-20471

Oxo- and hydroxo-bridged hexanuclear Ce(IV) clusters surrounded by 12 carboxylate ligands, Ce

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::81b33d06835bfbd5cdacb209672f0016
https://doi.org/10.1021/acs.inorgchem.2c03163

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Cerium(IV) Carboxylate Photocatalyst for Catalytic Radical Formation from Carboxylic Acids: Decarboxylative Oxygenation of Aliphatic Carboxylic Acids and Lactonization of Aromatic Carboxylic Acids

Autor: Tetsuya Satoh, Satoru Shirase, Kazushi Mashima, Keishi Hirosawa, Sota Tamaki, Koichi Shinohara, Hayato Tsurugi

Publikováno v: Journal of the American Chemical Society. 142(12)

We found that in situ generated cerium(IV) carboxylate generated by mixing the precursor Ce(OtBu)4 with the corresponding carboxylic acids served as efficient photocatalysts for the direct formation of carboxyl radicals from carboxylic acids under bl

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::91ebe28fd29c36f5f87ced719b4fb7c2
https://pubmed.ncbi.nlm.nih.gov/32109060

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