Zobrazeno 1 - 10
of 19
pro vyhledávání: '"Sophia A. Solomon"'
Publikováno v:
European Journal of Inorganic Chemistry. 2015:2041-2045
The relationship between phosphorus and carbon chemistry has been realized for many years. Phosphorus relatives of classical organic ligands (like cyclopentadienide, Cp–) in which carbon atoms have been substituted for phosphorus atoms are importan
Publikováno v:
European Journal of Inorganic Chemistry
Attempted synthesis of the ylide dianion [2,4,6-Me3C6H2P(CHR)3]2– (2,4,6-Me3C6H2 = mesityl, R = H or Me) by the reaction of mesitylphosphonium iodides [2,4,6-Me3C6H2PR3]+I– (R = Me, 1; R = Et, 2) with tBuLi at reflux does not result in the antici
Publikováno v:
Angewandte Chemie (International Ed. in English)
Vinyl boronates are extremely useful precursors, especially for the formation of new C–C bonds by cross-coupling and conjugate addition reactions.1, 2 Although alkyne hydroboration is a powerful synthetic route,3, 4 it is not applicable to the synt
Autor:
Matthew D. Helm, Alessandro Del Grosso, James R. Lawson, Viktor Bagutski, Michael J. Ingleson, Tommaso Marcelli, Sophia A. Solomon, Josue Ayuso Carrillo, Paul J. Singleton, Ian A. Cade
Publikováno v:
Journal of the American Chemical Society. 135:474-487
Direct electrophilic borylation using Y(2)BCl (Y(2) = Cl(2) or o-catecholato) with equimolar AlCl(3) and a tertiary amine has been applied to a wide range of arenes and heteroarenes. In situ functionalization of the ArBCl(2) products is possible with
Autor:
A. Del Grosso, Michael J. Ingleson, Sophia A. Solomon, Joseph J. W. McDouall, Viktor Bagutski, Ewan R. Clark
Publikováno v:
Organometallics. 31:1908-1916
Hydride abstraction from N,N′-bis(adamantyl)-1-hydrido-1,3,2-benzodiazaborole with catalytic [Ph3C][closo-CB11H6Br6] resulted in a low yield of arene borylation and a major product derived from migration of both adamantyl groups to the arene backbo
Autor:
Richard A. Layfield, Sophia A. Solomon
Publikováno v:
Dalton Trans.. 39:2469-2483
Metal allyl complexes in which the ligands carry bulky silyl substituents frequently show stability that cannot be achieved with unsubstituted analogues. As a result, it has been possible to characterize a large family of structurally diverse metal s
Publikováno v:
ChemInform. 46
A new high-yielding and direct route to the 1,2-diphospholide ligand framework using a very simple approach is presented.
Publikováno v:
ChemInform. 44
Vinyl boronates are extremely useful precursors, especially for the formation of new C–C bonds by cross-coupling and conjugate addition reactions.1, 2 Although alkyne hydroboration is a powerful synthetic route,3, 4 it is not applicable to the synt
Autor:
Sophia A. Solomon, Michael J. Ingleson, Matthew D. Helm, Dolores Caras-Quintero, Alessandro Del Grosso
Publikováno v:
ChemInform. 43
Electrophilic direct borylation is facilitated, and arene substrate scope enhanced, by using electrophiles derived from inexpensive reagents; specifically an amine, BCl3 and AlCl3.
Autor:
Alessandro Del Grosso, Matthew D. Helm, Dolores Caras-Quintero, Sophia A. Solomon, Michael J. Ingleson
Publikováno v:
Chemical communications (Cambridge, England). 47(46)
Electrophilic direct borylation is facilitated, and arene substrate scope enhanced, by using electrophiles derived from inexpensive reagents; specifically an amine, BCl(3) and AlCl(3).