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Autor:
Sophia A. Demoulini, Hasan Hicsasmaz, Randal M. Benefield, Jeffrey W. Bacon, James C. Faulhaber, Charles E. Flack, Brian Perry, Paul L. Gaus, Virginia B. Pett, Daniel E. Lynch, Jorge Villanueva
Publikováno v:
Inorganica Chimica Acta. 141:61-67
The outer sphere reductions of Co(NH3)5B3+ by Fe(CN)5A3− have been studied. The observed pseudo first order rate constants (Co complex in excess) obey the dependence kobs=Kosket[Co]/(1 +Kos[Co]), as expected for outer sphere electron transfer react