Zobrazeno 1 - 10
of 25
pro vyhledávání: '"Soline Sibille"'
Publikováno v:
The Journal of Organic Chemistry. 56:3255-3258
An efficient electrosynthesis of cyclopropanes from gem-dibromoalkanes and alkenes is achieved in a one-compartment cell fitted with a sacrificial zinc anode. The part played by the anodically generated Zn(II) in the coupling reaction is pointed out,
Publikováno v:
The Journal of Organic Chemistry. 56:2018-2024
The mechanism of the electroreductive coupling of α-chloro esters or α-chloro nitriles with carbonyl compounds by the means of a sacrificial zinc anode and a nickel catalyst was elucidated by electroanalytical techniques. The mechanism involved red
Autor:
Jean-Yves Nédélec, Jacques Perichon, Soline Sibille, Michel Troupel, J. Chaussard, Jean-Claude Folest
Publikováno v:
Synthesis. 1990:369-381
This article reviews the new possibilities in organic synthesis offered by the electroreduction of organic halides in the presence of various electrophiles using sacrificial metallic anodes
Autor:
Jacques Perichon, Jean-Yves Nédélec, Michel Troupel, J. Chaussard, Jean-Claude Folest, Soline Sibille
Publikováno v:
ChemInform. 21
This article reviews the new possibilities in organic synthesis offered by the electroreduction of organic halides in the presence of various electrophiles using sacrificial metallic anodes
Publikováno v:
ChemInform. 21
Trifluoroacetaldehyde, isolated as CF3CH(OCOCH3)2, is obtained in high yield by electroreduction of CF3Br in DMF, using an undivided cell and a sacrificial aluminium anode.
Publikováno v:
ChemInform. 21
The electroreductive coupling of trifluoromethylarenes with carbon dioxide, acetone, or N,N-dimethylformamide is achieved with good yields by electrolysis in an undivided cell fitted with a sacrificial anode.
Publikováno v:
J. Chem. Soc., Chem. Commun.. :283-284
Electroreduction of aromatic chlorides or bromides in a cell fitted with a sacrificial zinc anode, in the presence of a nickel, 2,2′-bipyridine complex affords the corresponding organozinc species in good yield.
Publikováno v:
J. Chem. Soc., Chem. Commun.. :53-54
The electrochemical cross-coupling of bromotrifluoromethane with aromatic or heteroaromatic iodides and bromides is successfully achieved in a one-compartment electrolysis cell fitted with a sacrifical copper anode.
Publikováno v:
J. Chem. Soc., Chem. Commun.. :48-49
β, γ-Unsaturated esters are obtained in moderate to good yields by a one-step electrochemical procedure from α-chloroesters and aryl or vinyl halides; a sacrificial aluminium anode, dimethylformamide as solvent, and a catalytic amount of nickel br
Autor:
Jacques Perichon, Jean-Marie Fuchs, José Coulombeix, André Mortreux, Francis Petit, Soline Sibille
Publikováno v:
Journal of Molecular Catalysis. 32:239-250
In propylene carbonate, electroreduction of Ni2+—PPh3—C2H4 mixtures affords a Ni(I) complex able to dimerize ethylene at room temperature under atmospheric pressure, mainly to 2-butenes. Starting from NiCl2-(PPh3)2, electrolysis in a one-compartm