Zobrazeno 1 - 10
of 63
pro vyhledávání: '"Soledad García-Fontán"'
Autor:
Mónica Martínez-Estévez, Soledad García-Fontán, Saray Argibay-Otero, Inmaculada Prieto, Ezequiel M. Vázquez-López
Publikováno v:
Molecules, Vol 27, Iss 22, p 7976 (2022)
The reaction of [Ru2Cl2(μ-Cl)2(η6-p-cymene)2] with two thiosemicarbazones obtained by the condensation of N-(4-methoxybenzyl) thiosemicarbazide and 1,4-hydroxy-3-methoxyphenyl)ethan-1-one (HL1) or 2-fluoro-4-hydroxybenzaldehyde (HL2) was studied. T
Externí odkaz:
https://doaj.org/article/b2495d1f327a4db0afbc95fdeb39861e
Financiaciado para publicación en acceso aberto: Universidade de Vigo/CISUG An alkenylphosphinite compound has been used to synthesize the unknown iridaoxaphospholane complexes which have been characterized in solution and solid state. The reactions
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::64e8e991652b5f5563f366677e1e60ca
https://hdl.handle.net/11093/4135
https://hdl.handle.net/11093/4135
Publikováno v:
Inorganica Chimica Acta. 519:120277
Half-sandwich mixed phosphine-phosphinite ruthenium complexes [RuCp’Cl(PPh3)L] [Cp’ = Cp (1), Cp* (2)], and [RuCp*ClL2] (3) were prepared by substitution of the triphenylphosphine by the phosphinite ligand PPh2OCH2Ph, L, on the parent complexes [
Publikováno v:
Polyhedron. 176:114288
New bromo- and chloro- tricarbonylrhenium(I) complexes [ReX(CO)3)L2] [X = Cl (1); Br(2)] containing the bifunctional phosphinite/ alkene ligand Ph2POCH2CH = CH2(L), have been prepared by reaction of the complexes[ReX(CO)5] (X = Cl, Br) with L, in ref
Autor:
Jorge Bravo, Gabriele Albertin, Gianluigi Zanardo, Nuria Álvarez-Pazos, Stefano Antoniutti, Jose M. Hermida-Ramón, Soledad García-Fontán
Trichlorostannyl complexes [Ru(SnCl3) (Cp')L] (2a-c) were prepared by treatment of optically active half-sandwich chlorocomplexes [RuCl(Cp')L] (1a-c) with an excess of SnCl2.2H2O in ethanol. Treatment of trichlorostannyl complexes 2a-c with NaBH4 aff
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::63430b3a2b1dc6a1616c94acbd98d1c3
http://hdl.handle.net/10278/3703121
http://hdl.handle.net/10278/3703121
Publikováno v:
European Journal of Inorganic Chemistry. 2015:4024-4031
A theoretical analysis was performed on reactions involving iridium alkoxycarbene complex [IrCp*Cl{=C(OCH3)CHCPh2}(PPh2Me)]PF6 (Cp* = pentamethylcyclopentadienyl), which can undergo aminolysis or heterolytic cleavage of the carbon(sp3)–oxygen bond.
Autor:
Jesús Castro, Soledad García-Fontán, Maria Talavera, Jose M. Hermida-Ramón, Jorge Bravo, Sandra Bolaño
Publikováno v:
Dalton Trans.. 43:17366-17374
Iridanaphthalene complexes are synthesized from the corresponding methoxy(alkenyl)carbeneiridium compounds. The electronic character of the substituents on the 6-position of the metallanaphthalene ring is crucial from the point of view of the stabili
Publikováno v:
Inorganica Chimica Acta. 495:118959
Reaction of [RuCl(η5-C5Me5)L] and [RuCl(η5-C9H7)L] (L = 1,2-[bis(diphenyl) phosphanyloxy]-1,2-diphenylethane) with an excess of GeCl2·dioxane afforded the half-sandwich trichlorogermyl complexes [Ru(GeCl3)(η5-C5Me5)L] (1a) and [Ru(GeCl3)(η5-C9H7
Publikováno v:
Organometallics. 32:7241-7244
The (methoxy)alkenylcarbeneiridium complexes [IrCp*Cl{═C(OMe)CH═CR1R2}L]PF6 (R1 = CH3, R2 = CH3, Ph; R1 = Ph, R2= H; L = PPh2Me, PMe3) can undergo an intramolecular C–H activation of one of the substituents R of the alkenyl fragment to give new
Autor:
Soledad García-Fontán, Jesús Castro, Sandra Bolaño, Jose M. Hermida-Ramón, Maria Talavera, Jorge Bravo
Publikováno v:
Organometallics. 32:4402-4408
The iridium methoxycarbene [IrCp*Cl{═C(OMe)CH═CPh2}(PPh2Me)]PF6 (3) can undergo a clean attack by nucleophiles at least by two different pathways: (1) an unusual nucleophilic attack of primary, secondary, and tertiary amines at the sp3 carbon–o