Structural and Dynamic Analysis of Sulphur Dioxide Adsorption in a Series of Zirconium‐Based Metal–Organic Frameworks.

Autor: Li, Jiangnan¹ (AUTHOR), Smith, Gemma L.¹ (AUTHOR), Chen, Yinlin¹ (AUTHOR), Ma, Yujie¹ (AUTHOR), Kippax‐Jones, Meredydd^1,2 (AUTHOR), Fan, Mengtian¹ (AUTHOR), Lu, Wanpeng¹ (AUTHOR), Frogley, Mark D.² (AUTHOR), Cinque, Gianfelice^2,3 (AUTHOR), Day, Sarah J.² (AUTHOR), Thompson, Stephen P.² (AUTHOR), Cheng, Yongqiang⁴ (AUTHOR), Daemen, Luke L.⁴ (AUTHOR), Ramirez‐Cuesta, Anibal J.⁴ (AUTHOR), Schröder, Martin¹ (AUTHOR) M.Schroder@manchester.ac.uk, Yang, Sihai¹ (AUTHOR) sihai.yang@manchester.ac.uk

Publikováno v: Angewandte Chemie. 9/5/2022, Vol. 134 Issue 36, p1-9. 9p.

Purification of Propylene and Ethylene by a Robust Metal-Organic Framework Mediated by Host-Guest Interactions

Autor: Li, Jiangnan, Han, Xue, Kang, Xinchen, Chen, Yinlin, Xu, Shaojun, Smith, Gemma L, Tillotson, Evan, Cheng, Yongqiang, McCormick McPherson, Laura J, Teat, Simon J, Rudić, Svemir, Ramirez-Cuesta, Anibal J, Haigh, Sarah J, Schröder, Martin, Yang, Sihai

Publikováno v: Angewandte Chemie (International ed. in English), vol 60, iss 28

Industrial purification of propylene and ethylene requires cryogenic distillation and selective hydrogenation over palladium catalysts to remove propane, ethane and/or trace amounts of acetylene. Here, we report the excellent separation of equimolar

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Host–guest selectivity in a series of isoreticular metal–organic frameworks: observation of acetylene-to-alkyne and carbon dioxide-to-amide interactions

Autor: Humby, Jack D., Benson, Oguarabau, Smith, Gemma L., Argent, Stephen P., da Silva, Ivan, Cheng, Yongqiang, Rudi?, Svemir, Manuel, Pascal, Frogley, Mark D., Cinque, Gianfelice, Saunders, Lucy K., Whitehead, George F. S., Easun, Timothy L., Lewis, William, Blake, Alexander J., Ramirez-Cuesta, Anibal J., Yang, Sihai

In order to develop new porous materials for applications in gas separations such as natural gas upgrading, landfill gas processing and acetylene purification it is vital to gain understanding of host-substrate interactions at a molecular level. Here

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=core_ac_uk__::8140f94e79801a438f0bdfab71b55049

Enhancement of CO2 Uptake and Selectivity in a Metal-Organic Framework by the Incorporation of Thiophene Functionality

Autor: Bolotov, Vsevolod A., Kovalenko, Konstantin A., Samsonenko, Denis G., Han, Xue, Zhang, Xinran, Smith, Gemma L., M'Cormick, Laura J., Teat, Simon J., Yang, Sihai, Lennox, Matthew J., Henley, Alice, Besley, Elena, Fedin, Vladimir P., Dybtsev, Danil N., Schroder, Martin

Publikováno v: Inorganic chemistry, vol 57, iss 9
Bolotov, V A, Kovalenko, K A, Samsonenko, D G, Han, X, Zhang, X, Smith, G L, M'Cormick, L J, Teat, S J, Yang, S, Lennox, M J, Henley, A, Besley, E, Fedin, V P, Dybtsev, D N & Schroder, M 2018, ' Enhancement of CO2 Uptake and Selectivity in a Metal-Organic Framework by the Incorporation of Thiophene Functionality ' Inorganic Chemistry . https://doi.org/10.1021/acs.inorgchem.8b00138
Bolotov, V A, Kovalenko, K A, Samsonenko, D G, Han, X, Zhang, X, Smith, G L, M'Cormick, L J, Teat, S J, Yang, S, Lennox, M J, Henley, A, Besley, E, Fedin, V P, Dybtsev, D N & Schroder, M 2018, ' Enhancement of CO2 Uptake and Selectivity in a Metal-Organic Framework by the Incorporation of Thiophene Functionality ', Inorganic Chemistry, vol. 57, no. 9, pp. 5074-5082 . https://doi.org/10.1021/acs.inorgchem.8b00138

The complex [Zn2(tdc)2dabco] (H2tdc = thiophene-2,5-dicarboxylic acid; dabco = 1,4-diazabicyclooctane) shows a remarkable increase in carbon dioxide (CO2) uptake and CO2/dinitrogen (N2) selectivity compared to the nonthiophene analogue [Zn2(bdc)2dabc

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::f1e1ca5aa6a6fd7eb87bfb4ecefa8e44
https://escholarship.org/uc/item/2f60x4h6