Zobrazeno 1 - 10
of 225
pro vyhledávání: '"Slavi C. Sevov"'
Autor:
Slavi C. Sevov, Luis G. Perla
Publikováno v:
Journal of the American Chemical Society. 138:9795-9798
We report the synthesis and characterization of the title anion which has a germanium/palladium cluster core of [Ge18Pd3] and six tri-isopropyl tin substituents. Its two Ge9-halves are the first examples of germanium deltahedra with three nonsilyl su
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d822ba12124d64e546cc22eadaaac32d
https://doi.org/10.1021/jacs.6b06545
https://doi.org/10.1021/jacs.6b06545
Autor:
Luis G. Perla, Slavi C. Sevov
Publikováno v:
Angewandte Chemie. 128:6833-6836
The title anion was synthesized by heating dimethylformamide (DMF) solution of the known Ni-centered and Ni(CO)-capped tin clusters [Ni@Sn9 Ni(CO)](3-) . The new anion represents the first example of face-fused nine-atom molecular clusters. The two c
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::98306f07717fd2f0b2e6e135a229f8f5
https://doi.org/10.1002/ange.201602837
https://doi.org/10.1002/ange.201602837
Publikováno v:
Journal of the American Chemical Society. 139(42)
We report the synthesis and characterization of the cluster anions [Ge
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::874d0ef3060bb372ef26ea75eae630de
https://pubmed.ncbi.nlm.nih.gov/28976192
https://pubmed.ncbi.nlm.nih.gov/28976192
Publikováno v:
Inorganic Chemistry. 54:872-875
The synthesis and structure of Bi(7)(3-), the only missing member of the family of heptanuclear pnictogen cluster anions Pn(7)(3-) (Pn = pnictogen, a group 15 element excluding the unique nitrogen), is reported. The new species is synthesized by oxid
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3ef92b7f23eb4c2292838562ac5ecbf3
https://doi.org/10.1021/ic502158e
https://doi.org/10.1021/ic502158e
Autor:
Slavi C. Sevov, Michael W. Hull
Publikováno v:
Journal of Organometallic Chemistry. :85-91
Deltahedral Zintl ions Ge94- are disubstituted with organic fragments that have various functional groups. Some of the latter are appropriate for coordination to transition-metals to eventually form coordination compounds where the organo-Zintl speci
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::78090d464815a6717b216951c5e7abac
https://doi.org/10.1016/j.jorganchem.2012.05.006
https://doi.org/10.1016/j.jorganchem.2012.05.006
Autor:
Slavi C. Sevov, Jose M. Goicoechea
Deltahedral nine-atom clusters of silicon, Si(9)(2-), were synthesized by mild oxidation of a liquid ammonia solution of K(12)Si(17) with Ph(3)GeCl in the presence of 18-crown-6 (1,4,7,10,13,16-hexaoxacyclooctadecane) or 2,2,2-crypt (4,7,13,16,21,24-
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6740a1f6e2a05f1491c38784d98e1158
https://ora.ox.ac.uk/objects/uuid:6059ea54-e60b-47ab-bc4a-d847097efc14
https://ora.ox.ac.uk/objects/uuid:6059ea54-e60b-47ab-bc4a-d847097efc14
Autor:
Jose M. Goicoechea, Slavi C. Sevov and
This review focuses on the reactivity of nine-atom deltahedral clusters of group 14, also known as deltahedral Zintl ions, toward various main-group and transition-metal compounds. The redox chemistry of these species and their ability to form oligom
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::452f1bee26dfbe4f13604e517077d854
https://ora.ox.ac.uk/objects/uuid:69d08f97-950e-474a-bdda-f428c8c654e8
https://ora.ox.ac.uk/objects/uuid:69d08f97-950e-474a-bdda-f428c8c654e8
Publikováno v:
Angewandte Chemie International Edition
Artículos CONICYT
CONICYT Chile
instacron:CONICYT
Artículos CONICYT
CONICYT Chile
instacron:CONICYT
The title compound, which has a ten-atom deltahedral cluster core of Ge9 Pd, was synthesized through insertion of Pd(PPh3 ) into the tetrasubstituted nona-germanium cluster [(Me3 Si)Si]3 EtGe9 through a reaction of the latter with Pd(PPh3 )4 . This f
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::084c9db87df734eeb9b9bc9700d6eaa6
https://pubmed.ncbi.nlm.nih.gov/27243908
https://pubmed.ncbi.nlm.nih.gov/27243908
Publikováno v:
Angewandte Chemie. 124:8709-8712
Reaching neutral territory: The title compound, the first tetrasubstituted deltahedral Zintl cluster, is no longer an ion (see picture; Ge green, Si purple, Sn blue). It is a neutral molecule formed by a reaction of the trisilylated anion with Ph(3)
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::064731297c8cc908725a5a9792e659d8
https://doi.org/10.1002/ange.201202906
https://doi.org/10.1002/ange.201202906
Publikováno v:
Crystal Growth & Design. 12:2684-2690
Reported is the synthesis and characterization of guest-free and guest-included frameworks assembled from the anionic metal complex [Fe(ox)3]3- and the cationic diprotonated 4,4′-bipyridinium2+ (H2bpy) or 1,2-bis(4-pyridinium)ethylene2+ (H2bpye) li
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a5d17e402650fe2baa2b613dcd91c076
https://doi.org/10.1021/cg300293j
https://doi.org/10.1021/cg300293j