Zobrazeno 1 - 10
of 30
pro vyhledávání: '"Sirish K. Reddy"'
Autor:
Sirish K. Reddy, Harini Kilambi, Jeffrey W. Stansbury, Lauren Schneidewind, Christopher N. Bowman
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 47:4859-4870
The impact of secondary functionalities on the radical-vinyl chemistry of monoacrylates characterized by secondary functionalities that dramatically enhance their polymerization rate was elucidated utilizing experimental and computational techniques.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7e13d8d7c9410aefa498fb21e860e066
https://doi.org/10.1002/pola.23503
https://doi.org/10.1002/pola.23503
Publikováno v:
Macromolecules. 40:6131-6135
In this particular study, the reaction mechanisms of bulk polymerization of acrylates in the presence of tetraethylthiuram disulfide (TED) are investigated using hexyl acrylate as a model acrylate. TED's presence impacts the termination mechanisms of
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a11f315e8cf9c9109950e80295a99557
https://doi.org/10.1021/ma070187f
https://doi.org/10.1021/ma070187f
Autor:
Tai Yeon Lee, Sirish K. Reddy, Christopher N. Bowman, Harini Kilambi, Jeffrey W. Stansbury, Lauren Schneidewind
Publikováno v:
Macromolecules. 40:6112-6118
This study focuses on the design and development of novel monovinylic (meth)acrylate monomers with enhanced polymerization kinetics and the evaluation of their performance as reactive diluents in diacrylate systems. Novel (meth)acrylic monomers chara
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::072d7db64bec9613811a9e6817c6b743
https://doi.org/10.1021/ma062708p
https://doi.org/10.1021/ma062708p
Publikováno v:
Polymer. 48:4589-4600
Degradable thiol-ene photopolymer networks were formed through radically mediated step growth reactions. Variations in the network structure were used to alter the initial and temporal moduli, mass loss profiles, and equilibrium swelling ratios. Mass
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b84c34e985bd03cc797fb44d59729518
https://doi.org/10.1016/j.polymer.2007.05.063
https://doi.org/10.1016/j.polymer.2007.05.063
Autor:
Jeffrey W. Stansbury, Sirish K. Reddy, Christopher N. Bowman, Harini Kilambi, Lauren Schneidewind
Publikováno v:
Polymer. 48:2014-2021
The copolymerization behavior and the dark polymerization kinetics of highly reactive novel acrylic monomers were compared to traditional acrylate monomers. Copolymerization of thiol functionalities with novel acrylic monomers was characterized, and
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8f2f242bb068de3ceed52b17d921ba06
https://doi.org/10.1016/j.polymer.2007.02.006
https://doi.org/10.1016/j.polymer.2007.02.006
Publikováno v:
Macromolecules. 40:1466-1472
The polymerization mechanism of the ternary thiol−allyl ether−methacrylate monomer system has been investigated. The effects of various factors including the thiol concentration, functionality, and structure on the polymerization mechanism, the p
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2271a5421ad39fceda3494bc8ba45e6f
https://doi.org/10.1021/ma062494b
https://doi.org/10.1021/ma062494b
Publikováno v:
Sensors and Actuators B: Chemical. 120:473-480
The ability to form low-moduli materials with sensitive modulus control over a wide range is advantageous for a variety of applications, including membranes and valves for microfluidic devices. This paper examines the impact of monomer functionality
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::fcee04f6ecc118627c8e075d7b5b52e2
https://doi.org/10.1016/j.snb.2006.02.040
https://doi.org/10.1016/j.snb.2006.02.040
Publikováno v:
Macromolecules. 39:8832-8843
In this study, we develop a modeling framework based on combined kinetic and statistical modeling approaches to describe pregelation and postgelation network properties of polymerization kinetics dependent mixed step-chain growth polymerizations. Spe
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::961baaa6e37c67625a1a302b3961fc42
https://doi.org/10.1021/ma060249m
https://doi.org/10.1021/ma060249m
Publikováno v:
Biomacromolecules. 7:2827-2836
Degradable thiol-acrylate materials were synthesized from the mixed-mode polymerization of a diacrylate poly(ethylene glycol) (PEG) monomer with thiol monomers of varying functionalities to control the final network structure, ultimately influencing
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b5ecf84d7503e9b81fe72286389faa58
https://doi.org/10.1021/bm0603793
https://doi.org/10.1021/bm0603793
Publikováno v:
Macromolecules. 39:3681-3687
A framework is developed to understand and predict the photopolymerization kinetics of ternary thiol−vinyl systems: thiol−ene−ene and thiol−ene−acrylate. Ternary thiol−vinyl photopolymerization systems of thiol−allyl ether−norbornene,
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b5ddcd1d5df71e952b2b484ec522876f
https://doi.org/10.1021/ma0600097
https://doi.org/10.1021/ma0600097