Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Sinja Manck"'
Publikováno v:
European Journal of Inorganic Chemistry. 2017:477-482
The ferrocene moiety with its well-defined redox behavior and its substitution potential is ideally suited for the assembly of multinuclear complexes. Utilizing the “click” strategy, we present here mono- and disubstituted pyridyl–triazolyl–f
Publikováno v:
Organometallics. 34:5393-5400
Noninnocent ligands are special because of their ability to act as electron reservoirs and tune reactivity at a metal center “on-demand”. In the following we present two iridium(III) complexes with a diamidobenzene ligand: one that is coordinativ
Autor:
Sinja Manck, Biprajit Sarkar
Publikováno v:
Topics in Catalysis. 58:751-758
Paramagnetic species are ubiquitous intermediates in many different reactions involving chemical bond activation and catalysis. Despite this fact, the use of electron paramagnetic resonance (EPR) spectroscopy for unraveling reaction mechanisms for ho
Autor:
Biprajit Sarkar, Sivathmeehan Yogendra, Christian Schwickert, Jan J. Weigand, Jens Müller, Jutta Kösters, Rainer Pöttgen, Sinja Manck, Johannes Neugebauer, Christian Radunsky, Matthias C. Letzel
Publikováno v:
European Journal of Inorganic Chemistry. 2015:4006-4012
A CuII hydrazone complex has been synthesized that can be reduced in situ in boiling methanol to give the corresponding CuI complex. The latter complex readily activates dioxygen under ambient conditions, as was unambiguously shown by isotopic labeli
Publikováno v:
Chemical Communications. 51:10949-10952
A mesoionic carbene with a ferrocene backbone is used as a metalloligand to generate the first example of their Fe–Au heterobimetallic complexes. The details of geometric and electronic structures in different redox states and preliminary catalytic
Autor:
Biprajit Sarkar, Sinja Manck
Publikováno v:
ChemInform. 46
Paramagnetic species are ubiquitous intermediates in many different reactions involving chemical bond activation and catalysis. Despite this fact, the use of electron paramagnetic resonance (EPR) spectroscopy for unraveling reaction mechanisms for ho
Autor:
Biprajit Sarkar, Stephan Hohloch, Sinja Manck, Vanessa S. Radtke, Fritz Weisser, Felix Führer, Margarethe van der Meer, Sebastian Plebst, Daniel Leichnitz
Publikováno v:
Inorganic chemistry. 54(10)
Activating chemical bonds through external triggers and understanding the underlying mechanism are at the heart of developing molecules with catalytic and switchable functions. Thermal, photochemical, and electrochemical bond activation pathways are