Two Types of Liquid Phase Separation Induced by Soft Centrifugation in Aqueous Ethyl Acetate Using Ethanol as Cosolvent

Autor: Helmut Cölfen, Rose Rosenberg, Dirk Haffke, Simon Stemplinger, Thomas Zemb, Dominik Horinek

Publikováno v: Research, Vol 6 (2023)

Water/ethyl acetate/ethanol is widely used as a “green” extractant system. We show that 2 different types of phase separation can be induced upon centrifugation in this ternary system using ethanol as a cosolvent of water and ethyl acetate: centr

Externí odkaz: https://doaj.org/article/d854b97509284af8a1bbdb12cd97b67d

Molecular dynamics simulations of Eu(NO3)3 salt with DMDOHEMA in n-alkanes: Unravelling curvature properties in liquid-liquid extraction

Autor: Simon Stemplinger, Magali Duvail, Jean-François Dufrêche

Publikováno v: Journal of Molecular Liquids
Journal of Molecular Liquids, Elsevier, In press, pp.118035. ⟨10.1016/j.molliq.2021.118035⟩
Journal of Molecular Liquids, 2022, 348, pp.118035. ⟨10.1016/j.molliq.2021.118035⟩

The spontaneous packing parameter and the bending rigidity of small reverse aggregates similar to reverse micelles in different diluents have been investigated. The considered system consisting of a common extractant (DMDOHEMA), a lanthanide salt (Eu

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bb7bd9052d3248c78bb7621a438765b0
https://doi.org/10.1016/j.molliq.2021.118035