Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Simon N. Thorn"'
Autor:
Sharn Ramaya, Graham B. Bloomberg, Alan J. Pearce, Timothy Gallagher, Simon N. Thorn, Daryl S. Walter
Publikováno v:
The Journal of Organic Chemistry. 64:5453-5462
The synthesis of the Fmoc-protected C-glycosyl tyrosines 1 and 2, together with two other related C-glycosyl tyrosines, has been achieved. Key reactions involved (i) the reaction of a glycal with an organozinc reagent (carrying an aryl iodide functio
Publikováno v:
Tetrahedron. 50:12211-12218
The barriers to interconversion of the stereomers of a number of N-cyano-O-phenylisoureas and related systems have been examined by variable temperature 1H NMR spectroscope. Rate constants were determined from the coalescence temperature using the Gu
Publikováno v:
Tetrahedron. 49:6885-6898
Hydrogenolysis of the benzyl ester 5 gave the imidazolone 6 rather than the desired acid 1, and the related benzyl ester 11 also hydrogenolysed to the imidazolone 12. Examination of the hydrolysis of simpler guanidine derivatives with trifluoroacetic
Publikováno v:
Tetrahedron. 49:165-176
The reaction of hydrazine with suitably substituted isoureas gives tetraazabicyclo[3.3.0]octanes. The products obtained in this reaction are extremely susceptible to the nature of the substrate and the reaction conditions, but a suitable combination
Publikováno v:
ChemInform. 22
The preference for 5- over 6-membered rings in the intramolecular cyclisation of amines with diesters can be partially overcome with mixed methyl (or benzyl), tert -butyl diesters, and this effect is enhanced where there is a β-substituent. The hexa
Publikováno v:
ChemInform. 24
The reaction of hydrazine with suitably substituted isoureas gives tetraazabicyclo[3.3.0]octanes. The products obtained in this reaction are extremely susceptible to the nature of the substrate and the reaction conditions, but a suitable combination
Publikováno v:
ChemInform. 24
Hydrogenolysis of the benzyl ester 5 gave the imidazolone 6 rather than the desired acid 1, and the related benzyl ester 11 also hydrogenolysed to the imidazolone 12. Examination of the hydrolysis of simpler guanidine derivatives with trifluoroacetic
Publikováno v:
ChemInform. 26
The barriers to interconversion of the stereomers of a number of N-cyano-O-phenylisoureas and related systems have been examined by variable temperature 1H NMR spectroscope. Rate constants were determined from the coalescence temperature using the Gu
Autor:
Timothy Gallagher, Simon N. Thorn
Publikováno v:
ChemInform. 27
Autor:
Sharn Ramaya, Timothy Gallagher, Alan J. Pearce, Daryl S. Walter, Graham B. Bloomberg, Simon N. Thorn
Publikováno v:
ChemInform. 30
The synthesis of the Fmoc-protected C-glycosyl tyrosines 1 and 2, together with two other related C-glycosyl tyrosines, has been achieved. Key reactions involved (i) the reaction of a glycal with an organozinc reagent (carrying an aryl iodide functio