Rate coefficients for the reaction of OH radicals with cis-3-hexene: an experimental and theoretical study

Autor: Javier Alejandro Barrera, Glauco F. Bauerfeldt, Graciela Arbilla, Thaís da Silva Barbosa, Silvia I. Lane, Juan Pablo Aranguren Abrate, Silvina Anahí Peirone

Publikováno v: Physical Chemistry Chemical Physics. 17:8714-8722

The kinetics of the cis-3-hexene + OH reaction were investigated by an experimental relative rate method and at the density functional theory level. The experimental set-up consisted of a 200 L Teflon bag, operated at atmospheric pressure and 298 K.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fef859c926d7ba6e097cce80df871e23
https://doi.org/10.1039/c4cp05760k

Rate Coefficient for the Reaction of Cl Atoms with cis-3-Hexene at 296 ± 2 K

Autor: Javier Alejandro Barrera, Rafael Jara Toro, Graciela Arbilla, Thaís da Silva Barbosa, Glauco F. Bauerfeldt, Silvia I. Lane

Publikováno v: Journal of the Brazilian Chemical Society v.28 n.11 2017
Journal of the Brazilian Chemical Society
Sociedade Brasileira de Química (SBQ)
instacron:SBQ
Journal of the Brazilian Chemical Society, Volume: 28, Issue: 11, Pages: 2267-2274, Published: NOV 2017
Journal of the Brazilian Chemical Society, Sociedade Brasileira de Química, SBQ, 2017, ⟨10.21577/0103-5053.20170078⟩
CONICET Digital (CONICET)
Consejo Nacional de Investigaciones Científicas y Técnicas
instacron:CONICET

The rate coefficient of the cis-3-hexene + Cl atoms reaction at 296 ± 2 K and 750 ± 10 Torr was determined using the relative rate technique. The reaction was investigated using an 80 L Teflon reaction bag and a gas chromatograph coupled with flame

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cfc962359eaf1fe0b1d39d831e1c6462
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017001102267

Relative rate coefficient measurements of OH radical reactions with (Z)-2-hexen-1-ol and (E)-3-hexen-1-ol under simulated atmospheric conditions

Autor: Pablo Marcelo Cometto, Silvia I. Lane, Javier Alejandro Barrera, Silvina Anahí Peirone, Raúl A. Taccone

Publikováno v: Atmospheric Environment. 85:92-98

The relative rate technique was used to determine the rate coefficients of the reactions of OH radicals with (Z)-2-hexen-1-ol (k1), and (E)-3-hexen-1-ol (k2), at (296 ± 2) K and (750 ± 10) Torr of N2 or pure air. The reactions were investigated usi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::adaa896a0c2dae6db6802d152aaee8bf
https://doi.org/10.1016/j.atmosenv.2013.11.076

Kinetic study of the OH-initiated photo-oxidation of four unsaturated (allyl and vinyl) ethers under simulated atmospheric conditions

Autor: Juan Pablo Aranguren Abrate, Silvina Anahí Peirone, Raúl A. Taccone, Pablo Marcelo Cometto, Silvia I. Lane

Publikováno v: Atmospheric Environment. 45:5325-5331

Using the relative rate technique, rate constants for the gas-phase reactions of hydroxyl radicals with n -propyl vinyl ether ( k 1 ), 2-chloroethyl vinyl ether ( k 2 ), allyl ether ( k 3 ) and allyl ethyl ether ( k 4 ) have been measured. Experiment

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e3d55c8efd14532e116582bfe3fba44c
https://doi.org/10.1016/j.atmosenv.2011.06.054

The photoinduced reaction of 2-iodothiophene in solutions of n-heptane, dichloromethane and methanol

Autor: Jorge D. Nieto, O. S. Herrera, A. C. Olleta, Silvia I. Lane

Publikováno v: Journal of Physical Organic Chemistry. 24:398-406

The photoinduced reaction of 2-iodothiophene in n-heptane, dichloromethane and methanol was studied at room temperature from experiments carried out with degassed solutions. The photoproducts of the reaction were mainly thiophene and small amounts of

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fe12fcdba2cbc0675a2041cb6a01b3ab
https://doi.org/10.1002/poc.1769