Zobrazeno 1 - 10
of 74
pro vyhledávání: '"Sidler, Dominik"'
Polaritonic chemistry has garnered increasing attention in recent years due to pioneering experimental results, which show that site- and bond-selective chemistry at room temperature is achievable through strong collective coupling to field fluctuati
Externí odkaz:
http://arxiv.org/abs/2409.08986
In this work we explore theoretically whether a parity-violating/chiral light-matter interaction is required to capture all relevant aspects of chiral polaritonics or if a parity-conserving/achiral theory is sufficient (e.g. long-wavelength/dipole ap
Externí odkaz:
http://arxiv.org/abs/2408.16695
Analytical results are presented for a model system consisting of an ensemble of N molecules under vibrational strong coupling (VSC). The single bare molecular model is composed of one effective electron, which couples harmonically to multiple nuclei
Externí odkaz:
http://arxiv.org/abs/2401.16374
Autor:
Schnappinger, Thomas, Sidler, Dominik, Ruggenthaler, Michael, Rubio, Angel, Kowalewski, Markus
Publikováno v:
J. Phys. Chem. Lett. 2023, 14, 8024 (2023)
Experimental studies indicate that optical cavities can affect chemical reactions, through either vibrational or electronic strong coupling and the quantized cavity modes. However, the current understanding of the interplay between molecules and conf
Externí odkaz:
http://arxiv.org/abs/2307.02208
Autor:
Sidler, Dominik, Schnappinger, Thomas, Obzhirov, Anatoly, Ruggenthaler, Michael, Kowalewski, Markus, Rubio, Angel
Publikováno v:
J. Phys. Chem. Lett. 15, 5208 (2024)
We demonstrate that collective vibrational strong coupling of molecules in thermal equilibrium can give rise to significant local electronic polarizations in the thermodynamic limit. We do so by first showing that the full non-relativistic Pauli-Fier
Externí odkaz:
http://arxiv.org/abs/2306.06004
The effect of spin-orbit (and Darwin) interaction on a 2D electron gas subject to a radial symmetric, inhomogeneous $1/r$-magnetic field is discussed analytically in a perturbative and non-perturbative manner. For this purpose, we investigate the rad
Externí odkaz:
http://arxiv.org/abs/2303.01286
In this review we present the theoretical foundations and first principles frameworks to describe quantum matter within quantum electrodynamics (QED) in the low-energy regime. Having a rigorous and fully quantized description of interacting photons,
Externí odkaz:
http://arxiv.org/abs/2211.04241
The first exact quantum simulation of a real molecular system (HD$^+$) under strong ro-vibrational coupling to a quantized optical cavity mode in thermal equilibrium is presented. Theoretical challenges in describing strongly coupled systems of mixed
Externí odkaz:
http://arxiv.org/abs/2208.01326
An analytic closed form solution is derived for the bound states of electrons subject to a static, inhomogeneous ($1/r$-decaying) magnetic field, including the Zeeman interaction. The solution provides access to many-body properties of a two-dimensio
Externí odkaz:
http://arxiv.org/abs/2201.05069
This perspective provides a brief introduction into the theoretical complexity of polaritonic chemistry, which emerges from the hybrid nature of strongly coupled light-matter states. To tackle this complexity, the importance of ab initio methods is h
Externí odkaz:
http://arxiv.org/abs/2108.12244