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Akademický článek

Electrocatalytic carbon dioxide reduction: from fundamental principles to catalyst design

Autor: Xiaolong Zhang, Si-Xuan Guo, Karl A. Gandionco, Alan M. Bond, Jie Zhang

Publikováno v: Materials Today Advances, Vol 7, Iss , Pp 100074- (2020)

Electrocatalytic reduction of carbon dioxide (CO2) is one of the most promising technologies available to mitigate environmental problems introduced by the continuous increase in its concentration that has occurred since the industrial revolution. Th

Externí odkaz: https://doaj.org/article/a26374c30e504fb78226039b4469a244

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Selective Electrochemical Hydrogenation of Phenol with Earth‐abundant Ni−MoO 2 Heterostructured Catalysts: Effect of Oxygen Vacancy on Product Selectivity

Autor: Peng Zhou, Si‐Xuan Guo, Linbo Li, Tadaharu Ueda, Yoshinori Nishiwaki, Liang Huang, Zehui Zhang, Jie Zhang

Publikováno v: Angewandte Chemie. 135

Herein, we report highly efficient carbon supported Ni-MoO2 heterostructured catalysts for the electrochemical hydrogenation (ECH) of phenol in 0.10 M aqueous sulfuric acid (pH = 0.7) at 60 °C. Highest yields for cyclohexanol and cyclohexanone of 95

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bdeda8d9c34e3cf0baaea9182717a3c3
https://doi.org/10.1002/ange.202214881

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Impact of the Lithium Cation on the Voltammetry and Spectroscopy of [XVM

Autor: Toru, Konishi, Keisuke, Kodani, Takuya, Hasegawa, Shuhei, Ogo, Si-Xuan, Guo, John F, Boas, Jie, Zhang, Alan M, Bond, Tadaharu, Ueda

Publikováno v: Inorganic chemistry. 59(15)

Polyoxometalates (POMs) have been proposed as electromaterials for lithium-based batteries because they provide access to multiple electron transfer reactions coupled to fast lithium ion transport processes and high stability over many redox cycles.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::e0d1db9398a3aee362992f13f612ef02
https://pubmed.ncbi.nlm.nih.gov/32786655

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Unprecedented Formation of a Binuclear Au(II)-Au(II) Complex through Redox State Cycling: Electrochemical Interconversion of Au(I)-Au(I), Au(II)-Au(II), and Au(I)-Au(III) in Binuclear Complexes Containing the Carbanionic Ligand C

Autor: Chencheng, Sun, Nedaossadat, Mirzadeh, Si-Xuan, Guo, Jiezhen, Li, Zhengkui, Li, Alan M, Bond, Jie, Zhang, Suresh K, Bhargava

Publikováno v: Inorganic chemistry. 58(20)

The rational design of binuclear Au(I)-Au(I), Au(II)-Au(II), and Au(I)-Au(III) complexes requires an understanding of how the redox states interconvert. Herein, the electrochemical interconversion of the three oxidation states I, II, and III is repor

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::6af48b1cc9ef6035a4c38324e4ad92f3
https://pubmed.ncbi.nlm.nih.gov/31573192

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Phosphomolybdic Acid-Assisted Growth of Ultrathin Bismuth Nanosheets for Enhanced Electrocatalytic Reduction of CO

Autor: Si-Xuan, Guo, Ying, Zhang, Xiaolong, Zhang, Christopher D, Easton, Douglas R, MacFarlane, Jie, Zhang

Publikováno v: ChemSusChem. 12(5)

Oxides containing two-dimensional metallic catalysts have shown enhanced catalytic activity, stability, and product selectivity. Porous three-dimensional structures maximize the accessibility of the active sites, thus enhancing the catalytic performa

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::f91ca167a190466dfe4ae54b5ae825b9
https://pubmed.ncbi.nlm.nih.gov/30648342

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