Zobrazeno 1 - 10
of 11
pro vyhledávání: '"Shyh-Ing Pien"'
Autor:
Steven S. C. Chuang, Shyh Ing Pien
Publikováno v:
ChemInform. 22
The synthesis of acetaldehyde and propionaldehyde from CO hydrogenation over NaMnNi catalysts has been studied. Coprecipitated NaMnNi catalysts exhibited high activities for the synthesis of acetaldehyde from CO hydrogenation and the synt
Autor:
Steven S. C. Chuang, Shyh-Ing Pien
Publikováno v:
Journal of Catalysis. 138:536-546
The effect of silver promotion on CO hydrogenation and ethylene hydroformylation over Rh/SiO2 has been studied. Catalyst characterization before reaction reveals that Ag and Rh form separate crystallites; part of the Ag is atomically spread on the su
Autor:
Shyh Ing Pien, Steven S. C. Chuang
Publikováno v:
Journal of Catalysis. 135:618-634
The reaction of adsorbed CO with C2H4/H2 and ethylene hydroformylation over reduced, oxidized, and sulfided Rh/SiO2 catalysts has been investigated under reaction conditions by in situ infrared spectroscopy. Both reactions involve the CO insertion st
Autor:
Shyh-Ing Pien, Steven S. C. Chuang
Publikováno v:
Journal of Molecular Catalysis. 68:313-330
Ethylene hydroformylation, CO hydrogenation and CO adsorption on RU/SiO2 and sulfided RU/SiO2 were studied by in situ infrared spectroscopy. Ethylene hydroformylation was shown to occur on the surface of Ru/SiO2 and sulfided Ru/SiO2 catalysts. Increa
Autor:
Steven S. C. Chuang, Shyh Ing Pien
Publikováno v:
Journal of Catalysis. 128:569-573
The synthesis of acetaldehyde and propionaldehyde from CO hydrogenation over NaMnNi catalysts has been studied. Coprecipitated NaMnNi catalysts exhibited high activities for the synthesis of acetaldehyde from CO hydrogenation and the synt
Autor:
Yee Soong, Steven S. C. Chuang, R.R. Schehl, Shyh-Ing Pien, Kanchan Ghosal, Richard P. Noceti
Publikováno v:
Applied Catalysis. 70:101-114
The effect of catalyst preparation methods on carbon monoxide hydrogenation selectivity over na-mn-ni catalysts has been studied. the sio2-supported ni and mn-ni catalysts prepared from impregnation exhibited high methanation and hydrocarbon synthesi
Publikováno v:
Journal of Catalysis. 126:187-191
The effect of H2S on ethylene addition to CO hydrogenation has been studied over Ni/SiO2, Rh/ SiO2, and Ru/SiO2 catalysts at 300°C and 10 atm. The major products of the ethylene addition on the unsulfided catalysts are ethane and propionaldehyde whi
Autor:
Steven S. C. Chuang, Shyh Ing Pien
Publikováno v:
Catalysis Letters. 6:389-393
Sulfidation of Ni/SiO2 with H2S leads to a blockage of bridge-CO sites, an upward shift in the wavenumber of linearly adsorbed CO, an inhibition of ethylene hydrogenation, and an enhancement of the formation of propionaldehyde from ethylene hydroform
Publikováno v:
Applied Catalysis. 57:241-251
The effect of silver on carbon monoxide hydrogenation over Rh/SiO2 has been studied. Silver is found to decrease the rates of formation for methane and C2+ hydrocarbons more than those for C2 oxygenates resulting in a marked increase in C2 oxygenate
Autor:
Shyh-Ing Pien, Steven S. C. Chuang
Publikováno v:
Journal of Molecular Catalysis. 55:12-22
An in situ IR technique combining selective sulfur poisoning was employed to study the reaction of an olefin with syngas to form an aldehyde (heterogeneous hydroformylation) on Rh/SiO 2 catalysts. In situ IR observation provides evidence for adsorbed