Zobrazeno 1 - 10
of 33
pro vyhledávání: '"Shuyou Chen"'
Publikováno v:
Dianxin kexue, Vol 37, Pp 18-26 (2021)
Caching popular video into user-side in advance improves the user experience and reduces operator costs, which is a common practice in the industry.How to effectively predict the popularity of videos has become a hot issue in the industry.On account
Externí odkaz:
https://doaj.org/article/7d2cfe66aa5c4342a4e73c11f0487b4a
Publikováno v:
Nature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
Enantioenriched medium-sized silicon-stereogenic heterocycles are in high demand due to the potential use in functional materials. Here, the authors show a rhodium-catalyzed enantioselective synthesis of six- and seven-membered tri-organosubstituted
Externí odkaz:
https://doaj.org/article/e18bfca0d9cd44e487b14b10aa4f75bb
Publikováno v:
Journal of the American Chemical Society. 143:5301-5307
A rhodium-catalyzed enantioselective construction of triorgano-substituted silicon-stereogenic siloxanes and alkoxysilanes is developed. This process undergoes a direct intermolecular dehydrogenative Si-O coupling between dihydrosilanes with silanols
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::eb058a45a08a885d784e3f650abbd184
https://doi.org/10.1021/jacs.1c01106
https://doi.org/10.1021/jacs.1c01106
Publikováno v:
Angewandte Chemie International Edition. 61
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::75abcc3e81e05603258394c639edf470
https://doi.org/10.1002/anie.202282161
https://doi.org/10.1002/anie.202282161
Publikováno v:
Journal of the American Chemical Society. 142:13459-13468
A rhodium-catalyzed tandem enantioselective C-H silylation/alkene hydrosilylation of dihydrosilanes, which enables the streamlined construction of a wide range of silicon-stereogenic silanes, is successfully developed. This process involves a SiH2-st
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ab39a9a56eaa72373b7fd767fbc719d5
https://doi.org/10.1021/jacs.0c04863
https://doi.org/10.1021/jacs.0c04863
Publikováno v:
Angewandte Chemie. 134
Intermolecular C-H silylation for the synthesis of acyclic silanes bearing a silicon-stereogenic center in one enantiomeric form remains unknown to date. Herein, we report the first enantioselective intermolecular C-H silylation of heteroarenes for t
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4997aea46447699567f5bc62b53f826e
https://doi.org/10.1002/ange.202117820
https://doi.org/10.1002/ange.202117820
Publikováno v:
ACS Catalysis. 9:6372-6379
The development of a rational strategy to achieve the complete regioselectivity and the capability to switch regioselectivity is an appealing, yet challenging, puzzle in transition-metal-catalyzed ...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2a7278fe0108942ee87b4c6897892369
https://doi.org/10.1021/acscatal.9b01273
https://doi.org/10.1021/acscatal.9b01273
Autor:
Jingbo Lan, Mangang Zhang, Shuyou Chen, Wenbo Liang, Zheng Liu, Yudong Yang, Xingwen Pu, Jingsong You, Min Zhang
Publikováno v:
Organic Letters. 21:1139-1143
Disclosed herein is a highly efficient one-pot synthetic strategy to phenanthrone-type polyheterocycles via tandem rhodium(III)-catalyzed ortho-C–H heteroarylation of indolyl ketones and copper(II)-promoted intramolecular cyclization. This protocol
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2eecff923a3ba1cbfb305e225602b464
https://doi.org/10.1021/acs.orglett.9b00089
https://doi.org/10.1021/acs.orglett.9b00089
A rhodium-catalyzed enantioselective construction of six- and seven-membered triorgano-substituted silicon-stereogenic heterocycles is developed. This process undergoes a direct dehydrogenative C−H silylation, giving access to a wide range of novel
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a912f935eae8b572c505b792c1aa9afc
https://doi.org/10.21203/rs.3.rs-108883/v1
https://doi.org/10.21203/rs.3.rs-108883/v1
Publikováno v:
Nature Communications
Nature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
Nature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
The exploitation of chirality at silicon in asymmetric catalysis is one of the most intriguing and challenging tasks in synthetic chemistry. In particular, construction of enantioenriched mediem-sized silicon-stereogenic heterocycles is highly attrac
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::be793a9b478c227db183edfc971c95b6
https://pubmed.ncbi.nlm.nih.gov/33623025
https://pubmed.ncbi.nlm.nih.gov/33623025