Kinetics and mechanism of the oxidation of a heterocyclic thioamide by silver(II)-cyclam

Autor: Shu-Chin Shen, Mahmud Roziahanim, Henry N. Po, Chosu Khin, Monica Weiss

Publikováno v: Journal of Coordination Chemistry. 57:1015-1026

The kinetics of the oxidation of 4,6-dimethyl-2-mercaptopyrimidine (DMP) by Ag(cyclam)2+ were studied in buffer solutions from pH 5.8 to 7.2 at constant ionic strength of 0.10 M (NaClO4). The reaction is observed to be first-order with respect to [Ag

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::0c74bf64b048c2791e10df59a1ebd229
https://doi.org/10.1080/00958970412331281755

STRUCTURE OF (RAC-5,5,7,12,12,14-HEXAMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE)SILVER(II) DIPERCHLORATE DIHYDRATE

Autor: Shu-Chin Shen, R. J. Doedens, H. N. Po

Publikováno v: PO, HN; SHEN, SC; & DOEDENS, RJ. (1993). STRUCTURE OF (RAC-5,5,7,12,12,14-HEXAMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE)SILVER(II) DIPERCHLORATE DIHYDRATE. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 49, 1914-1916. doi: 10.1107/S0108270193004342. UC Irvine: Retrieved from: http://www.escholarship.org/uc/item/9b133785

C C(1) C(2) C(3) C(4) C(5) C(6) C(7) C(8) REGULAR STRUCTURAL PAPERS Toby, B. H., Hughey, J. L. IV, Fawcett, T. G., Potenza, J. A. & Schugar, H. J. (1981). Acta Crvst. B37, 1737-1738. Whimp, P. O., Bailey, M. F. & Curtis, N. F. (1970). J. Chem. Soc. A

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http://www.escholarship.org/uc/item/9b133785

Kinetics and Mechanism of the Oxidation of 4-Methyl-2-Mercaptopyrimidine by Silver(II)-Cyclam and the Thermodynamics of its Acid-Base Reaction.

Autor: Po, Henry N., Hunting, Janet L., Mahmud, Roziahanim, Radzian, Rosidah, Shen, Shu-Chin

Publikováno v: Journal of Coordination Chemistry; Oct2000, Vol. 51 Issue 2, p399-416, 18p