Zobrazeno 1 - 10
of 112
pro vyhledávání: '"Shouji Iwatsuki"'
Publikováno v:
Journal of Polymer Science Part C: Polymer Symposia. 23:753-759
The microstructure of the copolymer of butadiene with maleic anhydride has been shown by IR spectra to be rich in cis-1,4 structure (about 70% at 60°C.), whereas the butadiene homopolymer by radical mechanism is rich in trans-1,4 structure. The copo
Publikováno v:
Designed Monomers and Polymers. 2:311-324
7,8-Bis(benzyloxycarbonyl)-7,8-dicyanoquinodimethane (1d) was prepared successfully as isolable crystals at room temperature and determined to have an anti-form by 1H-NMR spectroscopy. When 1d was dissolved in basic polar solvents such as acetonitril
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 36:1929-1936
1,4-Dicarbonyl-1,4-dihydronaphthalene (1) was synthesized by the dehydrochlorination reaction of 1,4-dihydronaphthalene-1,4-dicarbonyl chloride with triethylamine and obtained as its very dilute solution, but it easily polymerized in the concentratio
Autor:
Takeshi Hishida, Takahito Itoh, Masataka Kubo, Nobuaki Kamei, Hiroyuki Okuno, Shouji Iwatsuki, Akira Inokuchi, T. Sato
Publikováno v:
Tetrahedron. 53:15247-15261
Attempts were made to prepare novel 7-alkoxycarbonyl-7,8,8-tricyanoquinodimethanes (ethoxy(5a), isopropoxy(5b), and tert-butoxy(6c)), 7,7-bis(alkoxycarbonyl)-8,8-dicyanoquinodimethanes (ethoxy(6a), isopropoxy(6b), and tert-butoxy(6c)), and 1-(2,2-dim
Autor:
Takahito Itoh, Shouji Iwatsuki
Publikováno v:
Macromolecular Chemistry and Physics. 198:1997-2016
This article describes the polymerization behavior of electron-accepting substituted quinodimethanes. Chlorine-substituted quinodimethanes (la-c) behave differently depending on the number of chlorine substituents. Strong electron-accepting substitut
Publikováno v:
Polymer Bulletin. 37:155-160
Titanium-induced dicarbonyl-coupling reaction of 5-hexyloxybenzo[c]thiophene-1,3-dicarbaldehyde (9) was carried out to obtain poly(5-hexyloxybenzo[c]thiophene-1,3-diylvinylene) (10), which was characterized by 1H NMR, IR, UV-vis, and elemental analys
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 34:963-969
7,7-Bis(methoxycarbonyl)-, 7,7-bis(ethoxycarbonyl)-, and 7,7-bis(isopropoxycarbonyl)-1,4-benzoquinone methides (4a, 4b, and 4c) were successfully prepared as pure, isolable yellow-orange needles. The values of the first reduction potential for 4a, 4b
Publikováno v:
Macromolecules. 28:8363-8367
The Wittig reactions of 2,5-bis(dodecyloxy)-p-xylylenebis(triphenylphosphonium bromide) (6c) with thiophene-2,5-dicarbaldehyde (1a), selenophene-2,5-dicarbaldehyde (1b), tellurophene-2,5-dicarbaldehyde (1c), and benzo[c]thiophene-1,3-dicarbaldehyde (
Publikováno v:
Polymer Bulletin. 35:615-619
Vapor deposition polymerization of 1,9-bis(trimethylsilyloxy)[2.2]paracyclophane (Me3SiO-PC) was carried out to obtain poly(7-trimethylsilyloxy-p-xylylene) (Me3SiO-PPX) as a colorless tough film. The Me3SiO-PPX film was successfully converted to poly
Publikováno v:
Polymer Bulletin. 35:307-313
The polymerizations of three nitrogen-containing heterophanes such as [2.2](2,5)pyridinophane (1), [2.2](2,5)pyrazinophane (2) and N, N′-dimethyl-[2.2](2,5)pyrrolophane (3) by the vapor deposition method were carried out. Compounds1, 2 and3 gave po