Zobrazeno 1 - 9
of 9
pro vyhledávání: '"Shougo Takahashi"'
Publikováno v:
Catalysts, Vol 3, Iss 1, Pp 137-147 (2013)
Catalysts; Volume 3; Issue 1; Pages: 137-147
Catalysts; Volume 3; Issue 1; Pages: 137-147
In heterogeneous Ziegler-Natta catalysts for olefin polymerization, isolation of a single type of active sites is a kind of ambition, which would solve long-standing questions on the relationship between active site and polymer structures. In this pa
Autor:
Toshiaki Taniike, Shougo Takahashi, Minoru Terano, Sumant Dwivedi, Kiwamu Tonosaki, Toru Wada
Publikováno v:
Macromolecular Symposia. :1-7
Model catalysts having specially designed active species on support surfaces were employed to understand relationships between the structure/state of active sites and their catalytic performances for two classes of industrial olefin polymerization ca
Autor:
Toshiaki Taniike, Minoru Terano, Thang Quoc Vu, Binh Tien Nguyen, Mitsuhiro Ikeya, Shougo Takahashi
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 49:4005-4012
We have kinetically elucidated the origins of activity enhancement because of the addition of comonomer in Ziegler- Natta propylene polymerization, using stopped-flow and continu- ously purged polymerization. Stopped-flow polymerization (with the pol
Publikováno v:
Drug Metabolism and Pharmacokinetics. 26:30-46
Growing evidence indicates that the innate immune system and oxidative stress caused by gut-derived endotoxins play a key role in alcoholic liver disease (ALD). Intracellular mechanisms associated with endotoxin-induced signaling play a crucial role
Publikováno v:
Macromolecular Research. 18:839-844
The deactivation behaviors of TiCl3/MgCl2 model catalysts with molecularly dispersed TiCl3 were investigated to clarify the role of the dispersion state of the Ti species in the deactivation of MgCl2-supported Ziegler-Natta (ZN) catalysts for propyle
Publikováno v:
Macromolecular Research. 18(9):834-838
The dispersion state of surface Ti species is one of the most important factors for polymerization properties of MgCl_2-supported heterogeneous Ziegler-Natta catalysts. In this paper, ethylene-propylene copolymerization was conducted using a novel Zi
Publikováno v:
Macromolecular Reaction Engineering. 11:1600038
The origin of the chemical composition of ethylene/propylene copolymer produced with Ziegler–Natta catalysts is investigated in terms of the active site nature and transient monomer concentration during polymerization. Using various catalysts inclu
Publikováno v:
Macromolecular rapid communications. 30(11)
In propylene polymerization with MgCl(2) -supported Ziegler-Natta catalysts, it is known that the reduction of TiCl(4) with alkylaluminum generates Ti(3+) active species, and at the same time, leads to the growth of TiCl(x) aggregates. In this study,
Publikováno v:
Journal of Acupuncture and Meridian Studies. (1):43-48
Cold intolerance is an inability to tolerate cold temperatures and is accompanied by symptoms including headache, shoulder discomfort, dizziness and palpitations. The current study was performed to examine whether reflexology therapy affected cold in