Zobrazeno 1 - 10
of 12
pro vyhledávání: '"Shiro Ebata"'
Publikováno v:
Tetrahedron. 71:4413-4417
Intramolecular arylcyanation across a tri-substituted double bond proceeds to give a primary alkyl cyanide product through functionalization of C–CN and allylic C–H bonds and double C–C bond formation in a 1,3-manner by cooperative nickel/AlMe2
Publikováno v:
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN. 83(10):1170-1184
Lewis acid cocatalysts such as organoaluminum and -boron compounds dramatically improve the efficiency of the nickel-catalyzed arylcyanation of alkynes. Electron-rich aryl cyanides, which exhibit p...
Publikováno v:
ChemInform. 46
Publikováno v:
SYNLETT. (11):1709-1711
Enantioselective intramolecular arylcyanation of olefins is achieved by a Ni(cod) 2 /chiral phosphinoxazoline/AlMe 2 Cl catalyst to give chiral, substituted indoline derivatives bearing a benzylic quaternary stereocenter in high yields with good to e
Publikováno v:
ChemInform. 42
Lewis acid cocatalysts like organoaluminum and -boron compounds accelerate the catalytic cycle of the arylcyanation, allowing for expansion of the scope of aryl cyanides.
Publikováno v:
ChemInform. 41
Conditions A) in combination with chiral phosphinooxazoline ligands allows the enantioselective preparation of 3,3-disubstituted indolines, which represent biologically interesting substructures of alkaloids.
Publikováno v:
Journal of the American Chemical Society. 130(39)
A catalyst system derived from nickel and cocatalytic AlMe2Cl effects the intramolecular arylcyanation of alkenes. The reaction takes place in an exclusive exo-dig manner to give a wide range of nitriles having a benzylic quaternary carbon in good yi
Publikováno v:
Chemistry Letters. 36:606-607
The title reaction is found to proceed in the presence of a palladium catalyst and in the absence of any activator. Various functional groups are tolerated to give a diverse range of 1,4-diene and ...
Publikováno v:
Journal of the American Chemical Society. 129:2428-2429
Lewis-acid catalysts such as AlMe3, AlMe2Cl, and BPh3 significantly improve the efficiency of the nickel-catalyzed arylcyanation of alkynes. Electron-rich aryl cyanides, which exhibit poor reactivity in the absence of Lewis acids, readily undergo the
Publikováno v:
CHEMISTRY LETTERS. 35(7):790-791
Aryl cyanides add to norbornene and norbornadiene under nickel catalysis to give (2R*,3S*)-3-aryl-2-cyanobicyclo[2.2.1]heptanes and (2R*,3S*)-3-aryl-2-cyanobicyclo[2.2.1]hept-5-enes in good yields ...