Zobrazeno 1 - 10
of 25
pro vyhledávání: '"Shinji Nishii"'
Publikováno v:
Tetrahedron. 56:2821-2831
The diastereoselectivity in the conjugate addition of organocopper reagents to γ-aryl α,β-unsaturated carbonyl derivatives 8–14 was investigated. The syn -diastereoselectivity was obtained irrespective of the reagents type in the addition of 8,
Publikováno v:
ChemInform. 23
The chiral steroidal acetals 2(S–R, R isomer) and 3(S–S, S isomer) were prepared from the reaction of the steroidal aldehyde 1 with (2R, 4R)-(–)-pentane-2,4-diol and with (2S, 4S)-(+)-pentane-2,4-diol, respectively. The TiCl4 mediated reaction
Publikováno v:
ChemInform. 24
Publikováno v:
Journal of the American Chemical Society. 114:7652-7660
Systematic investigations of the diatereoselectivity of organocopper conjugate addition to γ-alkoxy trans enoates (3), cis enoates (4), and diesters (5) revealed that the selectivity highly depended on the substrate structure and the reagent type. T
Publikováno v:
ChemInform. 32
The diastereoselectivity in the conjugate addition of organocopper reagents to γ-aryl α,β-unsaturated carbonyl derivatives 8–14 was investigated. The syn -diastereoselectivity was obtained irrespective of the reagents type in the addition of 8,
Publikováno v:
ChemInform. 21
Publikováno v:
The Journal of Organic Chemistry. 54:4055-4061
La reaction de t-butyldimethylsiloxy mesyloxy pentene-2oate ou -butyrate de methyle avec des cuprates donne les t-butyldimethylsiloxy alkyl pentene-3oates ou -hexene-3oates de methyle. La reaction est effectuee egalement sur des pentoses proteges en
Publikováno v:
Journal of the American Chemical Society. 111:4864-4872
Autor:
Yoshinori Yamamoto, Shinji Nishii
Publikováno v:
The Journal of Organic Chemistry. 53:3597-3603
Publikováno v:
The Journal of Organic Chemistry. 53:3947-3952
La reaction de t-butyldimethylsiloxy-3α pregnenes-17(20)- et -pregnadienes-5,17(20)oates d'ethyle avec des agents alkylants fournit principalement des methyl-20(S) pregnenes-16 ou -pregnadienes-5,16