Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Shin-Hong Lih"'
Publikováno v:
The Journal of Organic Chemistry. 63:2699-2704
An alpha-carbonyl radical cyclization approach toward synthesis of angular triquinanes is described. As a model study, conjugate addition of 4-(trimethylsilyl)-3-butynylmagnesium chloride to enone 7 followed by trapping of the enolate with chlorotrim
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::275dbce00b8d06078db7d54ce23972cb
https://doi.org/10.1021/jo9723570
https://doi.org/10.1021/jo9723570
Autor:
Wei‐Hong Tseng, Shih-Jung Huang, Ruey‐Torn Chiou, Shin-Hong Lih, Nei‐Tung Yau, Chin-Kang Sha, Jenn‐Fenn Young, Tsong‐Shin Jean
Publikováno v:
Pure and Applied Chemistry. 68:687-689
Intramolecular cyclization of α-carbonyl radicals to the trimethylsilylacetylenic side chain gives bicyclic vinylsilane ketones and enones. Application of this cyclization to total synthesis of (±)-modhephene is described.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f083124dd1fd85732032fbad8cbd1dd6
https://doi.org/10.1351/pac199668030687
https://doi.org/10.1351/pac199668030687
Publikováno v:
Journal of Organic Chemistry; 04/17/98, Vol. 63 Issue 8, p2699, 6p