Výsledky vyhledávání - "Shenglai Yao"

Diiron cofactors in enzymes perform diverse challenging transformations. The structures of high valent intermediates Q in methane monooxygenase and X in ribonucleotide reductase are debated since Fe amp; 8722;Fe distances of 2.5 3.4 amp; 8197; were a

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6a3c7bfad7a0e54b7cb62285f08ee6cd
https://pubmed.ncbi.nlm.nih.gov/36541062

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Non-aromatic 1,3-Disilapyrroles: a class of stable organosilicon-based triplet diradicals

Autor: Yun Xiong, Shicheng Dong, Shenglai Yao, Christian Lorent, Konstantin Krause, Vijaykumer Gonela, Jun Zhu, Christian Limberg, Matthias Driess

Open-shell molecules with unpaired electrons and a high-spin S ≥ 1 configuration are of fundamental importance in chemistry, biology and towards molecular electronics. Among metal-free systems, carbon- and silicon-based triplet diradicals with two

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::41b17f28b6d03c82e79f924d1b978fbb
https://doi.org/10.21203/rs.3.rs-2190177/v1

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An Isolable 2,5‐Disila‐3,4‐Diphosphapyrrole and a Conjugated Si=P−Si=P−Si=N Chain Through Degradation of White Phosphorus with a N,N ‐Bis(Silylenyl)Aniline

Autor: Yun Xiong, Shicheng Dong, Shenglai Yao, Chenshu Dai, Jun Zhu, Sebastian Kemper, Matthias Driess

Publikováno v: Angewandte Chemie International Edition. 61

White phosphorus (P

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5b8f837d2335111f83fe1541d353722e
https://doi.org/10.1002/anie.202209250

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The Heaviest Bottleable Metallylone: Synthesis of a Monatomic, Zero-Valent Lead Complex ('Plumbylone')

Autor: Jian Xu, Sudip Pan, Shenglai Yao, Gernot Frenking, Matthias Driess

Publikováno v: Angewandte Chemie (International ed. in English). 61(38)

The elusive plumbylone {[SiII(Xant)SiII]Pb0} 3 stabilized by the bis(silylene)xanthene chelating ligand 1, [SiII(Xant)SiII=PhC(NtBu)2Si(Xant)Si(NtBu)2CPh], and its isolable carbonyl iron complex {[SiII(Xant)SiII]Pb0Fe(CO)4} 4 are reported. The compou

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2db646d5348a288182ef21bcb739af04
https://pubmed.ncbi.nlm.nih.gov/35848899

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A bis(silylene)pyridine pincer ligand can stabilize mononuclear manganese(0) complexes: facile access to isolable analogues of the elusive d

Autor: Shweta, Kalra, Daniel, Pividori, Dominik, Fehn, Chenshu, Dai, Shicheng, Dong, Shenglai, Yao, Jun, Zhu, Karsten, Meyer, Matthias, Driess

Publikováno v: Chemical science. 13(29)

Using the potentially tridentate

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::4494215501b449896f0c1ba745288d4c
https://pubmed.ncbi.nlm.nih.gov/35974753

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New Types of Ge2 and Ge4 Assemblies Stabilized by a Carbanionic Dicarborandiyl-Silylene Ligand

Autor: Matthias Driess, Dandan Chen, Shenglai Yao, Yun Xiong, Jun Zhu, Ales Ruzicka

Publikováno v: Journal of the American Chemical Society. 143:6229-6237

The first Ge(0)-Ge(II) germylone-germylene-paired Ge2 complex (LSi)2Ge2 (4) and the molecular Ge4 cluster (LSi)2Ge4 (5) supported by the chelating carbanionic ortho-C,C'-dicarborandiyl-silylene ligand LSi [L = C,C'-C2B10H10, Si = PhC(tBuN)2Si] have b

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::ee0515cf5ad63de5a21df73b0b15ea75
https://doi.org/10.1021/jacs.1c01722

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