Zobrazeno 1 - 10
of 137
pro vyhledávání: '"Sheng-Hsien Chiu"'
Publikováno v:
Organic Letters. 24:1996-2001
We report the insertion of Pd(II) into an originally achiral rotaxane producing two chiral metallorotaxanes: one is planar-chiral, with its two interlocked components both chelating nonequivalently to the metal center; the other is
Autor:
Ching-Yu Chen, Chun-Ju Hsu, Chien-Chen Lai, Shie-Ming Peng, Tsung-Hsien Ho, Han-Chen Xu, Sheng-Hsien Chiu, Yi-Hung Liu
Publikováno v:
The Journal of Organic Chemistry. 86:13491-13502
In this study we found that 2,6-dimethanolpyridine displays good complementarity toward di(ethylene glycol) for the complexation of Na+ ions, allowing us to use this recognition system for the efficient synthesis of hetero[2]catenanes; indeed, it all
A Redox-Controllable Molecular Switch Based on Weak Recognition of BPX26C6 at a Diphenylurea Station
Publikováno v:
Molecules, Vol 20, Iss 2, Pp 1775-1787 (2015)
The Na+ ion–assisted recognition of urea derivatives by BPX26C6 has allowed the construction of a redox-controllable [2]rotaxane-type molecular switch based on two originally very weakly interacting host/guest systems. Using NOBF4 to oxidize the tr
Externí odkaz:
https://doaj.org/article/3152ee8861854111b3ea5995c0153432
Publikováno v:
Angewandte Chemie. 132:11374-11378
We have prepared NHC-CuI complexes with a rotaxane structure and used them as sterically sensitive catalysts for one-pot sequential copper-catalyzed azide/alkyne cycloadditions in solutions containing all of the coupling partners premixed in unprotec
Publikováno v:
Organic Letters. 21:5708-5712
The absolute configurations of the two enantiomers of a topologically chiral [2]catenane were determined unambiguously based on HPLC resolution and X-ray crystal analysis. Although structurally dissimilar to simple amino acids, the optical rotations
Autor:
Chien-Chen Lai, Ting-Hsuan Chiang, Cheng-Yen Tsou, Yu-Hsuan Chang, Sheng-Hsien Chiu, Richard P. Cheng
Publikováno v:
Organic letters. 23(15)
We report a new slippage system based on p-tert-butylbenzyl-terminated imidazolium ions and di(ethylene glycol)-containing macrocycles and their use as linking units for the construction of a prototypical molecular "Lock & Lock" box from a resorcinar
Publikováno v:
Journal of the Chinese Chemical Society. 66:134-145
Publikováno v:
Chemical communications (Cambridge, England). 56(35)
In this study imidazolium and imidazolinium centers in precursor [2]rotaxanes were deprotonated to obtain interlocked molecules featuring stabilized N-heterocyclic carbene centers. The encircling macrocyclic components enhanced the persistence of the
Publikováno v:
Accounts of Chemical Research. 51:1324-1337
In 1987, Pedersen, Cram, and Lehn were awarded the Nobel Prize in Chemistry to honor their achievements in, among other things, the selective recognition of alkali metal ions by synthetic hosts. Almost three decades later, the 2016 Nobel Prize went t
Autor:
Chi-You Tsai, Chien-Chen Lai, Yi-Hung Liu, Shie-Ming Peng, Richard P. Cheng, Sheng-Hsien Chiu
Publikováno v:
The Journal of Organic Chemistry. 83:5619-5628
Sodium ion-controlled switching from "folded" to "linear" states results in significant changes in the molecular shape of a [2]catenane, such that it mimics the operation of a gin trap, with a fluorescent alarm signal appearing when pyrene side arms