Zobrazeno 1 - 8
of 8
pro vyhledávání: '"Seyed-Mohammad H. Tabaei"'
Publikováno v:
Synthetic Communications. 30:43-51
The reaction in situ of sodium borohydride with 2-methoxyethanol in 2-propanol in the presence of catalytic amount of NiCl26H2O generates a powerful dechlorinating system which dechlorinates 1,1,1-trichloro-2,2-bis (4-chlorophenyl)-ethane (DDT) to 1,
Publikováno v:
Tetrahedron Letters. 34:3263-3266
Metal-promoted NaBH4 and NaBH2(OCH2CH2OCH3)2 dechlorinations were carried out on the aromatic chloro compounds pentachlorophenol and 1,2,4-trichlorobenzene. The best results were obtained by dropwise addition of NiCl2 in solution to NaBH2(OCH2CH2OCH3
Publikováno v:
Hazardous Waste and Hazardous Materials. 10:431-440
The reaction in situ of sodium borohydride with 2-methoxyethanol in THF generates NaBH2(OCH2CH2OCH3)2, which is a stronger dehalogenating agent than tetraethylene glycol (TEG)/KOH or TEG/ KOH/NaBH4 for chlorinated compounds. NaBH2(OCH2CH2OCH3)2 in TH
Publikováno v:
ChemInform. 24
Publikováno v:
ChemInform. 24
Publikováno v:
ChemInform. 31
The reaction in situ of sodium borohydride with 2-methoxyethanol in 2-propanol in the presence of catalytic amount of NiCl26H2O generates a powerful dechlorinating system which dechlorinates 1,1,1-trichloro-2,2-bis (4-chlorophenyl)-ethane (DDT) to 1,
Publikováno v:
Tetrahedron Letters. 32:2727-2730
Polyethylene glycol (PEG) or tetraethylene glycol (TEG)/KOH when used in combination with either sodium borohydride or alkoxyborohydrides give very powerful reducing media which quantitatively destroy Mirex at about 70°C. The reduction rate is furth
Publikováno v:
The Journal of Organic Chemistry. 57:6669-6671