Zobrazeno 1 - 10
of 53
pro vyhledávání: '"Sergii I, Shylin"'
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 80, Iss 1, Pp 25-28 (2024)
The synthetic availability of molecular water oxidation catalysts containing high-valent ions of 3d metals in the active site is a prerequisite to enabling photo- and electrochemical water splitting on a large scale. Herein, the synthesis and crystal
Externí odkaz:
https://doaj.org/article/d3ce286d0116445fb6175fcd22bc890c
Autor:
Stefania Tomyn, Sergii I. Shylin, Dmytro Bykov, Vadim Ksenofontov, Elzbieta Gumienna-Kontecka, Volodymyr Bon, Igor O. Fritsky
Publikováno v:
Nature Communications, Vol 8, Iss 1, Pp 1-9 (2017)
High-valent iron compounds do not form spontaneously under ambient conditions and those that are synthetically available are rarely stable. Here, the authors synthesize stable iron(IV) hexahydrazide clathrochelate complexes in aqueous media via a met
Externí odkaz:
https://doaj.org/article/28c81f6d1be441e18e86efb166d46302
Autor:
Yurii S. Bibik, Sergiu Shova, Aurelian Rotaru, Sergii I. Shylin, Igor O. Fritsky, Rostyslav D. Lampeka, Il’ya A. Gural’skiy
Publikováno v:
Inorganic Chemistry. 61:14761-14769
Hysteretic spin crossover in coordination complexes of 3d-metal ions represents one of the most spectacular phenomena of molecular bistability. In this paper we describe a self-assembly of pyrazine (pz) and Fe(BH
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1436e15f414cbfe70fa659a6a187f3f5
https://doi.org/10.1021/acs.inorgchem.2c02177
https://doi.org/10.1021/acs.inorgchem.2c02177
Autor:
Martin Panthöfer, Vadim Ksenofontov, Ute Kolb, Jörn Schmedt auf derGünne, Bastian Barton, Sergii I. Shylin, Ke Xu, Marcel Maslyk, Björn Meermann, Sven Bach, Wolfgang Tremel, Wenyu Li
Publikováno v:
The Journal of Physical Chemistry C. 125:2636-2647
Zinc phosphate, an important pigment in phosphate conversion coatings, forms protective films on rubbing surfaces. We have simulated the underlying reactions under shear by ball-milling zinc phosphate and monitored the reaction of hopeite (Zn3(PO4)2
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ada9e830cee4a2433afcc723d996aa6e
https://doi.org/10.1021/acs.jpcc.0c09044
https://doi.org/10.1021/acs.jpcc.0c09044
Autor:
Dina D. Naumova, Igor O. Fritsky, Aurelian Rotaru, Iryna S. Kuzevanova, Olesia I. Kucheriv, Il'ya A. Gural'skiy, Volodymyr M. Hiiuk, Sergii I. Shylin, Sergiu Shova, Volodymyr O. Kotsyubynsky
Publikováno v:
Dalton Transactions. 50:9250-9258
Hofmann-like cyanometallic complexes represent one of the biggest and well-known classes of FeIIspin-crossover compounds. In this paper, we report on the first FeIIHofmann clathrate analogues with unsubstituted 1,2,3-triazole, which exhibit temperatu
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::dd6ff503e89d27f2c0bc6e0b44cd1654
https://doi.org/10.1039/d1dt01544c
https://doi.org/10.1039/d1dt01544c
Autor:
Andriy Mokhir, Andrew Ozarowski, Alina O. Husak, Igor O. Fritsky, Frank Hampel, Sergii I. Shylin, Sergiu Shova, James Pogrebetsky, Dmytro Bykov, Elzbieta Gumienna-Kontecka
Publikováno v:
Chemical Communications. 57:11060-11063
Mn cage complexes are rare, and the ones successfully isolated in the solid state are not stable in water and organic solvents. Herein, we present the first report of mononuclear Mn clathrochelates, in which the encapsulated metal exists in the oxida
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ed1c1e50df9518a0b5d2c7e761c7df1a
https://doi.org/10.1039/d1cc04870h
https://doi.org/10.1039/d1cc04870h
Autor:
Bohdan O. Golub, Sergii I. Shylin, Sebastian Dechert, Maria L. Malysheva, Il`ya A. Gural`skiy
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 7, Pp 776-778 (2015)
The title salt, [FeII(C4H3ClN2)2(H2O)4](C7H7O3S)2, contains a complex cation with point group symmetry 2/m. The high-spin FeII cation is hexacoordinated by four symmetry-related water and two N-bound 2-chloropyrazine molecules in a trans arrangement,
Externí odkaz:
https://doaj.org/article/577d1630288241b5916698acd45c4f8d
Autor:
Olesia I. Kucheriv, Sergii I. Shylin, Tetiana A. Ilina, Sebastian Dechert, Il'ya A. Gural'skiy
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 4, Pp 374-376 (2015)
In the crystal of the title compound, [Fe(NCS)3(H2O)3]·3C6H8N2, the FeIII cation is located on a threefold rotation axis and is coordinated by three N atoms of the thiocyanate anions and three water molecules in a fac arrangement, forming a slightly
Externí odkaz:
https://doaj.org/article/5b902e73fed44faa9731bda1d8767863
Autor:
Olesia I. Kucheriv, Sergii I. Shylin, Valerii Y. Sirenko, Vadim Ksenofontov, Wolfgang Tremel, Ioan‐Andrei Dascălu, Sergiu Shova, Il'ya A. Gural'skiy
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 28(44)
Spin-crossover complexes with multistep transitions attract much attention due to their potential applications as multi-switches and for data storage. A four-step spin crossover is observed in the new iron(II)-based cyanometallic guest-free framework
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2021cf0da0a368ef49e40011a998fab7
https://pubmed.ncbi.nlm.nih.gov/35536105
https://pubmed.ncbi.nlm.nih.gov/35536105
Autor:
Volodymyr M, Hiiuk, Sergii I, Shylin, Diana D, Barakhtii, Dmytro M, Korytko, Volodymyr O, Kotsyubynsky, Aurelian, Rotaru, Sergiu, Shova, Il'ya A, Gural'skiy
Publikováno v:
Inorganic chemistry. 61(4)
Two 2D Hofmann-type complexes of the composition [Fe(Phpz)
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::6e5bfaa24573c99fe64647514e43daf6
https://pubmed.ncbi.nlm.nih.gov/35029111
https://pubmed.ncbi.nlm.nih.gov/35029111