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Autor:
Irene C. Keller, Walter Bauer, Ulrich Zenneck, Frank W. Heinemann, Christine Höhn, Tatyana E. Shubina, Lars Rohwer, Sergi Huguet Torrell
Publikováno v:
European Journal of Inorganic Chemistry. 2016:691-699
Cage-chiral P5-deltacyclene 1 is available as a pair of highly enriched P–C cage enantiomers 1′ and 1″, which exist as pairs of epimers a and b. Deprotonation of cage atom P1 initiates a rearrangement reaction, in which P1 and the neighboring c