Výsledky vyhledávání - "Sergelj I. Druzhinin"

Absence of intramolecular charge transfer with 4-fluoro-N,N-dimethylaniline (DMA4F), contrary to an experimental report supported by computations

Autor: Attila Demeter, Sergelj I. Druzhinin, Klaas A. Zachariasse

Publikováno v: Journal of Physical Chemistry A

With 4-fluoro-N,N-dimethylaniline (DMA4F), only a single fluorescence from a locally excited (LE) state is observed, irrespective of solvent polarity, temperature, and excitation wavelength. The relatively small excited state dipole moment mu(e) = 7.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::68d2137ba81e88822f393a3ec49de0b5
https://hdl.handle.net/11858/00-001M-0000-002D-0A54-C11858/00-001M-0000-002D-0A55-A11858/00-001M-0000-002D-0A52-0

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Intramolecular charge transfer with crystal violet lactone in acetonitrile as a function of temperature: reaction is not solvent-controlled

Autor: Attila Demeter, Sergelj I. Druzhinin, Klaas A. Zachariasse

Publikováno v: Journal of Physical Chemistry A

Intramolecular charge transfer (ICT) with crystal violet lactone (CVL) in the excited singlet state takes place in solvents more polar than n-hexane, such as ethyl acetate, tetrahydrofuran, and acetonitrile (MeCN). In these solvents, the fluorescence

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fe8e9bf25cb59d1c6f5a18bdf77845b2
https://pubmed.ncbi.nlm.nih.gov/23865629

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