Zobrazeno 1 - 8
of 8
pro vyhledávání: '"Sergei Krupski"'
Autor:
Ivana Císařová, Gerald Kehr, Zhongbao Jian, Gerhard Erker, Sergei Krupski, Constantin G. Daniliuc, Karel Škoch, Petr Štěpnička
Publikováno v:
Organometallics. 36:2940-2946
(Dimesitylphosphino)ferrocene (FcPMes2) (1) reacted with HB(C6F5)2 (2 equiv) by disproportionation to give adduct FcPMes2·H2B(C6F5) (4) plus B(C6F5)3, whereas 1-(dimesitylphosphino)-1′-vinylferrocene (2) was cleanly hydroborated with HB(C6F5)2 to
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0d4334e006faa06fc5ebf997465afebf
https://doi.org/10.1021/acs.organomet.7b00363
https://doi.org/10.1021/acs.organomet.7b00363
Autor:
Frederik Heins, Alexander Hepp, Constantin G. Daniliuc, Sergei Krupski, F. Ekkehardt Hahn, Johannes Neugebauer, Daniel Paul, Frank Glorius, Kevin Klahr
Publikováno v:
Organometallics. 36:1001-1008
The HOMO–LUMO energy gap of germylenes bearing CNHC∧Namido chelate ligands has been calculated in order to find suitable candidates for the activation of small molecules. Identified as promising structures, intramolecularly NHC-stabilized three-c
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d24ddab5ac5e3c948d0d5e0830a78ef7
https://doi.org/10.1021/acs.organomet.6b00925
https://doi.org/10.1021/acs.organomet.6b00925
Publikováno v:
Dalton Transactions. 45:6111-6117
Dimesitylphosphinoisoprene 9a reacts with a series of R-B(C6F5)2 boron Lewis acids by isomerization and subsequent 1,4-P/B addition to give the heterocyclic phosphonium/borate zwitterionic products 13. Subsequent hydride abstraction from the isopreny
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d2b361c418df34fb5a25dff7dde9e2fa
https://doi.org/10.1039/c5dt03879k
https://doi.org/10.1039/c5dt03879k
Autor:
Alexander Hepp, F. Ekkehardt Hahn, Christian Schulte to Brinke, Hannah Koppetz, Sergei Krupski
Publikováno v:
Organometallics. 34:2624-2631
The monoalkylated or monoarylated o-phenylenediamines 1a–d (1a, R = t-Bu; 1b, R = adamantyl; 1c, R = phenyl; 1d, R = mesityl) react via transamination with Ge[N(SiMe3)2]2 or Sn[N(SiMe3)2]2 to give the protic benzimidazolin-2-germylenes 2a–d or th
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::693d181f7cf34ca86a10c961dfc82dc6
https://doi.org/10.1021/om5012616
https://doi.org/10.1021/om5012616
Publikováno v:
Chemical Communications. 52:2695-2697
Reaction of the –CH2OSiMe3 substituted allyldimesitylphosphane 5 with HB(C6F5)2 resulted in a hydroboration/(C6F5)2BOSiMe3 elimination sequence to give the phosphinomethyl substituted cyclopropane derivative 9, probably via a phosphiranium type int
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::175a16857a98d44a8484e6bef7b039ce
https://doi.org/10.1039/c5cc09585a
https://doi.org/10.1039/c5cc09585a
Publikováno v:
Organometallics. 31:2078-2084
A rigid ditopic benzobisgermylene, 4a, was prepared by the reaction of the 1,2,4,5-tetra(alkylamine)benzene 3a and Ge[N(SiMe3)2]2. The analogous reaction of two 1,2,4,5-tetra(alkylamine)benzenes, 3b,c, with Sn[N(SiMe3)2]2 led to the oxidation of the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5273a5922a3a16165b0c545882a55101
https://doi.org/10.1021/om3000604
https://doi.org/10.1021/om3000604
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 43(1)
Four N,N′-disubstituted 1,2-diaminobenzes (1a: R = t-Bu, 1b: R = adamantyl, 1c: R = Ph, 1d: R = Dipp) have been prepared and reacted with E[N(SiMe3)2]2 (E = Ge, Sn) to give the benzannulated N-heterocyclic germylenes 2a–d and stannylenes 3a–d.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6ae97e2f1ed20b2a348fee6b51b5476d
https://pubmed.ncbi.nlm.nih.gov/24121532
https://pubmed.ncbi.nlm.nih.gov/24121532
Autor:
Sergei Krupski, Christian Schulte to Brinke, Hannah Koppetz, Alexander Hepp, F. Ekkehardt Hahn
Publikováno v:
Organometallics; Jun2015, Vol. 34 Issue 11, p2624-2631, 8p