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Autor:
Matthias, Golecki, Norman, Beyer, Gunther, Steinfeld, Vasile, Lozan, Sergei, Voitekhovich, Muhamed, Sehabi, Jens, Möllmer, Hans-Jörg, Krüger, Berthold, Kersting
Publikováno v:
Angewandte Chemie (International ed. in English). 53(37)
The macrocyclic complex [Ni2(L)(OAc)]ClO4 (1) adsorbs up to 17 molar equivalents (270 wt%) of iodine, although it does not exhibit permanent porosity. Vibrational spectroscopic and crystallographic studies reveal that two I2 molecules are captured by