Zobrazeno 1 - 10
of 146
pro vyhledávání: '"Serge I. Gorelsky"'
Publikováno v:
ACS macro letters. 4(1)
Direct (hetero)arylation polymerization (DHAP) shows great promise for simple, cheap, and environmentally benign preparation of conjugated polymers, but seems to involve a lack of selectivity when different aromatic C–H bonds are present. We report
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c4f43589da361d4d2dc7af011b5aa9e5
https://pubmed.ncbi.nlm.nih.gov/35596391
https://pubmed.ncbi.nlm.nih.gov/35596391
Autor:
Christina Dietz, Serge I. Gorelsky, Klaus Jurkschat, Sonja Herres-Pawlis, Thomas Zöller, Alexander Hoffmann, Florian Winter, Rainer Pöttgen
Publikováno v:
Chemistry - A European Journal. 24:5551-5561
Syntheses and molecular structures of the dimeric tin-platinum complex [LSnPtCl2 (SMe2 )]2 (2), the tin-platinum clusters [{LSnPtCl(SMe2 )}2 SnCl2 )] (3) and [(LSn)3 (PtCl2 )(PtClSnCl)(LSnOHCl)] (6) (L=MeN(CH2 CMe2 O- )2 ), and of the unprecedented t
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e28541b5a624e0d3adea69efd1141295
https://doi.org/10.1002/chem.201703520
https://doi.org/10.1002/chem.201703520
Autor:
Michael Rübhausen, Matthias Witte, Adam Neuba, Arne Goos, Uwe Gerstmann, Martin Bernard, Sonja Herres-Pawlis, Gerald Henkel, Wolf Gero Schmidt, Serge I. Gorelsky, Benjamin Grimm-Lebsanft, Stephan Binder
Publikováno v:
Journal of Computational Chemistry. 37:2181-2192
Density functional theory (DFT) and time-dependent DFT calculations are presented for the dicopper thiolate complex Cu2 (NGuaS)2 Cl2 [NGuaS=2-(1,1,3,3-tetramethylguanidino) benzenethiolate] with a special focus on the bonding mechanism of the Cu2 S2
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f7bab3cdd48adfa1d9baab744f741362
https://doi.org/10.1002/jcc.24439
https://doi.org/10.1002/jcc.24439
Publikováno v:
Chemistry - A European Journal. 22:8063-8067
Selective reactions between nucleophilic N,N'-diaryl-heterocyclic carbenes (NHCs) and electrophilic fluorinated alkenes afford NHC fluoroalkenes in high yields. These stable compounds undergo efficient and selective fluoride abstraction with Lewis ac
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0e122516069d8e63e597146070af3f23
https://doi.org/10.1002/chem.201601029
https://doi.org/10.1002/chem.201601029
Autor:
Jean-François Vincent-Rocan, Christian Clavette, Andre M. Beauchemin, Ryan A. Ivanovich, Serge I. Gorelsky, Jean‐Gregoire Roveda
Publikováno v:
Chemistry - A European Journal. 22:7906-7916
The ubiquity of nitrogen heterocycles in biologically active molecules challenges synthetic chemists to develop a variety of tools for their construction. While developing metal-free hydroamination reactions of hydrazine derivatives, it was discovere
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::41b14e79e875c5550b7d2a582d132797
https://doi.org/10.1002/chem.201600574
https://doi.org/10.1002/chem.201600574
Autor:
Serge I. Gorelsky
Molecular orbital theory and its fragment orbital approach allow computational chemists to analyze complicated wavefunctions using familiar and highly intuitive concepts of chemical bonding. In this chapter, we discuss electronic structure descriptor
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::917ca91c0704a57355bb698dd93c8d34
https://doi.org/10.1016/bs.adioch.2018.12.001
https://doi.org/10.1016/bs.adioch.2018.12.001
Autor:
Stephanie L. Daifuku, Uttam K. Das, Ilia Korobkov, Serge I. Gorelsky, Muralee Murugesu, Michael L. Neidig, R. Tom Baker, Jennifer J. Le Roy
Publikováno v:
Inorganic Chemistry. 55:987-997
The new tridentate ligand, S(Me)N(H)S = 2-(2-methylthiophenyl)benzothiazolidine, prepared in a single step from commercial precursors in excellent yield, undergoes ring-opening on treatment with Fe(OTf)2 in the presence of base affording a trinuclear
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a20fe9cea0420011ead1f97c08aa5951
https://doi.org/10.1021/acs.inorgchem.5b02833
https://doi.org/10.1021/acs.inorgchem.5b02833
Autor:
Serge I. Gorelsky, David A. Dixon, R. Tom Baker, Julia M. Bayne, Monica Vasiliu, Ilia Korobkov, Matthew C. Leclerc, Daniel J. Harrison, Graham M. Lee
Publikováno v:
Journal of the American Chemical Society. 137:16064-16073
Four perfluoroalkyl cobalt(III) fluoride complexes have been synthesized and characterized by elemental analysis, multinuclear NMR spectroscopy, X-ray crystallography, and powder X-ray diffraction. The remarkable cobalt fluoride (19)F NMR chemical sh
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e7f082b880085bb1dbc39ca3cbae6193
https://doi.org/10.1021/jacs.5b12003
https://doi.org/10.1021/jacs.5b12003
Publikováno v:
Organometallics. 34:1415-1418
The synthesis, structure, and magnetic properties of a uranium(III) sandwich complex, [Li(DME)3][UIII(COT″)2] (COT″ = bis(trimethylsilyl)cyclooctatetraenyl dianion), and its coordinatively analogous tetravalent equivalent, [UIV(COT″)2], were in
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::750306fe518d48b25b58fdedc5822083
https://doi.org/10.1021/om501214c
https://doi.org/10.1021/om501214c
Publikováno v:
Chemical Science. 6:6392-6397
A T-shaped octafluoronickelacyclopentane–NHC complex is prepared and characterized. While the solid-state structure includes a weak isopropyl-CH3 agostic interaction, the reactivity of this complex with Lewis- and Bronsted acids is clearly enhanced
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::976d94b113a8f470554570a4ab8c2e75
https://doi.org/10.1039/c5sc01886b
https://doi.org/10.1039/c5sc01886b