Zobrazeno 1 - 10
of 293
pro vyhledávání: '"Sensuke, Ogoshi"'
Publikováno v:
Nature Communications, Vol 15, Iss 1, Pp 1-11 (2024)
Abstract Cheminformatics-based machine learning (ML) has been employed to determine optimal reaction conditions, including catalyst structures, in the field of synthetic chemistry. However, such ML-focused strategies have remained largely unexplored
Externí odkaz:
https://doaj.org/article/b799602fe09d44ab8bcdd6874f892388
Publikováno v:
Tetrahedron Chem, Vol 9, Iss , Pp 100059- (2024)
Toward a more efficient use of crude H2 without its energy-consuming purification and/or composition regulation processes, this study employs gaseous mixtures of H2, CO, CO2, and CH4 for the catalytic hydrogenation of aldehydes and ketones in the pre
Externí odkaz:
https://doaj.org/article/b5b6b7b6b72f4ed785f2bba759d97cd8
Autor:
Yoichi Hoshimoto, Mahiro Sakuraba, Takuya Kinoshita, Masaki Ohbo, Manussada Ratanasak, Jun-ya Hasegawa, Sensuke Ogoshi
Publikováno v:
Communications Chemistry, Vol 4, Iss 1, Pp 1-6 (2021)
Frustrated Lewis pairs can be thermally revived from classical Lewis adducts, but the mechanism by which this occurs is not well understood. Here a combined experimental and theoretical study supports a pathway mediated by boron-jumping and dynamic c
Externí odkaz:
https://doaj.org/article/0b521bf3868344fdb2c03dfdeec5ed9f
Publikováno v:
Synthesis. 55:857-867
Tetrafluoroethylene (TFE) is an industrial organofluorine feedstock that is used predominantly to fabricate fluorinated polymers. TFE exhibits excellent potential as a building block for synthesizing organofluorine compounds, which are increasingly g
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::6a493bb7755a178e75df61924d00edc6
https://doi.org/10.1055/a-1983-5059
https://doi.org/10.1055/a-1983-5059
Publikováno v:
Chemistry Letters; Mar2024, Vol. 53 Issue 3, p1-10, 10p
Publikováno v:
Nature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
Tricyclic furanic compounds with multiple chiral centers are found in a variety of natural products. Here, the authors show a highly enantioselective nickel-catalyzed procedure to access tricyclic oxygen-containing scaffolds with five contiguous chir
Externí odkaz:
https://doaj.org/article/3c787649d39c4ad8b5b8b89e6d424d32
Autor:
Yoichi Hoshimoto, Yasuhiro Yamauchi, Yutaka Mondori, Yuta Uetake, Yasuo Takeichi, Takahiro Kawakita, Hidehiro Sakurai, Sensuke Ogoshi
Designing and modulating the electronic and spatial environment surrounding metal centers is a crucial issue in a wide range of chemistry fields that use organometallic compounds. Herein, we demonstrate a Lewis-acid-mediated reversible expansion, con
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::6c53892875907bbedfd14b5fdcf26539
https://doi.org/10.26434/chemrxiv-2023-5nz52
https://doi.org/10.26434/chemrxiv-2023-5nz52
Herein, we report the development of a nickel-catalyzed cross-coupling reaction of silyl difluoroenolates with aryl zinc reagents via C−F bond cleavage. Treatment of a stoichiometric amount of Ni(0)/ N-heterocyclic carbene (NHC) with silyl difluoro
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::9fd42d797a9c3f4c7e463d21b6891466
https://doi.org/10.26434/chemrxiv-2023-tszsc
https://doi.org/10.26434/chemrxiv-2023-tszsc
Autor:
Yasuhiro Yamauchi, Yoichi Hoshimoto, Takahiro Kawakita, Takuya Kinoshita, Yuta Uetake, Hidehiro Sakurai, Sensuke Ogoshi
Publikováno v:
Journal of the American Chemical Society. 144:8818-8826
Chemisorption on organometallic-based adsorbents is crucial for the controlled separation and long-term storage of gaseous molecules. The formation of covalent bonds between the metal centers in the adsorbents and the targeted gases affects the desor
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::855db45a176f8ddb2595a2ab091d38be
https://doi.org/10.1021/jacs.2c02870
https://doi.org/10.1021/jacs.2c02870
Perfluoroalkyl compounds are persistent environmental pollutants due to their strong C(sp3)−F bonds. Hydrodefluorination has emerged as a potential alternative disposal method for perfluoroalkyl compounds. Although the transformation of trifluorome
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1b1ad9b1d5d00889c30fb2e8efe8f601
https://doi.org/10.26434/chemrxiv-2023-9tkg4
https://doi.org/10.26434/chemrxiv-2023-9tkg4