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Autor:
Irek M. Gubaidullin, Leonard M. Khalilov, Usein M. Dzhemilev, Svetlana V. Pechatkina, Lyudmila V. Parfenova, Liya R. Abzalilova, Alexandr V. Balaev, Semyon I. Spivak
Publikováno v:
International Journal of Chemical Kinetics. 39:333-339
The mechanism of α-olefin hydroalumination by HAlBui2, ClAlBui2, and AlBui3 in the presence of Cp2ZrCl2 catalyst has been studied. It was established that the key intermediate of the reaction is a bimetallic complex [Cp2ZrH2 · ClAlBui2]2, which rea