An environmentally benign way to synthesize 2-thiocyano-1,3-dicarbonyl compounds with high antifungal activity: a key role of solvent.

Autor: Kirillov AS; N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation. vil@ioc.ac.ru., Semenov EA; N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation. vil@ioc.ac.ru., Bityukov OV; N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation. vil@ioc.ac.ru., Kuznetsova MA; All-Russian Research Institute for Phytopathology, B. Vyazyomy, 143050, Moscow Region, Russian Federation., Demidova VN; All-Russian Research Institute for Phytopathology, B. Vyazyomy, 143050, Moscow Region, Russian Federation., Rogozhin AN; All-Russian Research Institute for Phytopathology, B. Vyazyomy, 143050, Moscow Region, Russian Federation., Glinushkin AP; All-Russian Research Institute for Phytopathology, B. Vyazyomy, 143050, Moscow Region, Russian Federation., Vil' VA; N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation. vil@ioc.ac.ru., Terent'ev AO; N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation. vil@ioc.ac.ru.

Publikováno v: Organic & biomolecular chemistry [Org Biomol Chem] 2023 May 03; Vol. 21 (17), pp. 3615-3622. Date of Electronic Publication: 2023 May 03.

Synthesis of unstrained Criegee intermediates: inverse α-effect and other protective stereoelectronic forces can stop Baeyer-Villiger rearrangement of γ-hydroperoxy-γ-peroxylactones.

Autor: Vil' VA; N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences 47 Leninsky Prospect Moscow 119991 Russian Federation terentev@ioc.ac.ru., Barsegyan YA; N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences 47 Leninsky Prospect Moscow 119991 Russian Federation terentev@ioc.ac.ru., Kuhn L; Department of Chemistry and Biochemistry, Florida State University Tallahassee Fl 32306 USA ialabugin@fsu.edu., Ekimova MV; N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences 47 Leninsky Prospect Moscow 119991 Russian Federation terentev@ioc.ac.ru.; D. I. Mendeleev University of Chemical Technology of Russia 9 Miusskaya Square Moscow 125047 Russian Federation., Semenov EA; N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences 47 Leninsky Prospect Moscow 119991 Russian Federation terentev@ioc.ac.ru.; D. I. Mendeleev University of Chemical Technology of Russia 9 Miusskaya Square Moscow 125047 Russian Federation., Korlyukov AA; A. N. Nesmeyanov Institute of Organoelement Compounds Russian Academy of Sciences 28 Vavilov Street Moscow 119991 Russian Federation.; Pirogov Russian National Research Medical University Moscow 117997 Russian Federation., Terent'ev AO; N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences 47 Leninsky Prospect Moscow 119991 Russian Federation terentev@ioc.ac.ru., Alabugin IV; Department of Chemistry and Biochemistry, Florida State University Tallahassee Fl 32306 USA ialabugin@fsu.edu.

Publikováno v: Chemical science [Chem Sci] 2020 May 06; Vol. 11 (20), pp. 5313-5322. Date of Electronic Publication: 2020 May 06.