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Autor:
Selwin Fernando, Martina Landrini, Alceo Macchioni, David L. Hughes, Peter H. M. Budzelaar, Luca Rocchigiani
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 52(2)
σ-Bond metathesis between zirconocene cations and Cp2WH2 affords a bimetallic bridging hydride with an out of plane configuration and no M–M interaction. Small molecules react predominantly at the Zr-C bond in the absence of bimetallic cooperativi