Zobrazeno 1 - 10
of 116
pro vyhledávání: '"Selenenic acid"'
Publikováno v:
Molecules, Vol 20, Iss 12, Pp 21415-21420 (2015)
A primary-alkyl-substituted selenenyl iodide was successfully synthesized through oxidative iodination of a selenol with N-iodosuccinimide by taking advantage of a cavity-shaped steric protection group. The selenenyl iodide exhibited high thermal sta
Externí odkaz:
https://doaj.org/article/298337d59ad34ac6ac34302c327f9fea
Autor:
Oshini Ekanayake, Christopher W. am Ende, Samuel L. Scinto, Uthpala Seneviratne, Samantha J. Boyd, Michael T. Taylor, Sharon Rozovsky, Jessica E. Pigga, Jun Liu, Joseph M. Fox
Publikováno v:
Journal of the American Chemical Society. 141:10932-10937
Sulfenylation (RSH → RSOH) is a post-translational protein modification associated with cellular mechanisms for signal transduction and the regulation of reactive oxygen species. Protein sulfenic acids are challenging to identify and study due to t
Publikováno v:
New Journal of Chemistry. 43:6830-6833
A stable primary-alkyl-substituted selenenic acid was developed as a synthetic model of selenocysteine–derived selenenic acid (Sec–SeOH) by taking advantage of a huge cavity-shaped substituent. The primary-alkyl model compound was successfully ap
Autor:
Laura Orian, Leopold Flohé
Publikováno v:
Antioxidants
Antioxidants, Vol 10, Iss 1560, p 1560 (2021)
Antioxidants, Vol 10, Iss 1560, p 1560 (2021)
Among the chalcogens, selenium is the key element for catalyzed H2O2 reduction. In organic synthesis, catalytic amounts of organo mono- and di-selenides are largely used in different classes of oxidations, in which H2O2 alone is poorly efficient. Bio
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d1b6c88b4aea22923714f98cd3df3de1
http://hdl.handle.net/11577/3427647
http://hdl.handle.net/11577/3427647
Autor:
Giovanni Ribaudo, Davide Zeppilli, Laura Orian, Andrea Madabeni, Marco Bortoli, João Rocha, Pablo A. Nogara, Folorunsho Bright Omage
Publikováno v:
Catalysts, Vol 11, Iss 114, p 114 (2021)
Catalysts
Volume 11
Issue 1
Catalysts
Volume 11
Issue 1
Chalcogen-nitrogen chemistry deals with systems in which sulfur, selenium, or tellurium is linked to a nitrogen nucleus. This chemical motif is a key component of different functional structures, ranging from inorganic materials and polymers, to rati
Autor:
Luca Sancineto, Massimiliano Arca, Antonio L. Braga, Vanessa Nascimento, Michio Iwaoka, Francesca Marini, Vito Lippolis, Pâmella da Silva Cordeiro, Claudio Santi
Publikováno v:
New Journal of Chemistry
DFT calculations performed on amidoaryldiselenides as electrophilic derivatives evidenced the presence of a prevalent Se⋯O weak interaction when selenium is bonded to a Se atom (diselenides), a Br atom (selenenyl bromide) and an O atom (selenenic a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e1f9d368c6b093b7dad76ecf074219d0
http://hdl.handle.net/11391/1480173
http://hdl.handle.net/11391/1480173
Autor:
Astrid Borchert, Andrea Schmidt, Sophia Regina Roth, Marlena Rademacher, Jacqueline Kalms, Patrick Scheerer, Hartmut Kühn, Hermann-Georg Holzhütter
Publikováno v:
Biochimica et Biophysica Acta (BBA) - Molecular and Cell Biology of Lipids. 1863:1095-1107
Glutathione peroxidases (GPX) are anti-oxidative enzymes that reduce organic and inorganic hydroperoxides to the corresponding alcohols at the expense of reduced glutathione. The human genome involves eight GPX genes and five of them encode for selen
Autor:
Ramesh Kheirabadi, Mohammad Izadyar
Publikováno v:
Computational Biology and Chemistry. 75:213-221
The mechanism of action of the selenenamide 1 as a mimic of the glutathione peroxidase (GPx) was investigated by the density functional theory. The solvent-assisted proton exchange procedure was applied to model the catalytic behavior and antioxidant
Publikováno v:
Angewandte Chemie International Edition. 54:901-904
The unprecedented dehydration of a selenenic acid (RCH2SeOH) to a selenoaldehyde (RCH=Se) has been demonstrated. A primary-alkyl-substituted selenenic acid was synthesized for the first time by taking advantage of a bulky cavity-shaped substituent. U
Publikováno v:
Free Radical Biology and Medicine. 76:127-135
Selenenic acids are highly reactive intermediates of selenoproteins’ enzymatic reactions. Knowledge of how the protein environment protects and stabilizes them is fundamental not only to descriptions of selenoproteins’ reactivity but also potenti