Zobrazeno 1 - 10
of 26
pro vyhledávání: '"Sekai Iwama"'
Publikováno v:
Symmetry, Vol 2, Iss 1, Pp 112-135 (2010)
We report the mechanism and scope of “preferential enrichment”, which is an unusual symmetry-breaking enantiomeric resolution phenomenon that is initiated by the solvent-assisted solid-to-solid transformation of a metastable polymorphic form into
Externí odkaz:
https://doaj.org/article/f3920dccb6554e6c8681d6f7817690c5
Publikováno v:
Journal of Molecular Structure. 1245:131073
Two new hydrate cocrystals, (RS)-arginine-fumaric acid-H2O (2) and (S)-arginine-2 fumaric acid-H2O (3), were obtained by the slow evaporation of the saturated aqueous ethanol solution of a 1:1 mixture of S-enriched arginine (33% ee) and fumaric acid
Publikováno v:
Crystal Growth & Design. 15:3052-3062
The hydrogen bond motifs in the racemic crystals of the first-generation of chiral organic compounds, which showed a good to excellent preferential enrichment (PE) phenomenon, were rationalized by graph set analysis in terms of the selective dissolut
Autor:
Rajesh G. Gonnade, Hirohito Tsue, Rui Tamura, Sekai Iwama, Yoko Morita, Hiroki Takahashi, K. Manoj
Publikováno v:
Chirality. 27:405-410
By utilizing the preferential enrichment (PE) technique, we achieved an improved enantiomeric resolution of DL-leucine (Leu) using a 1:1 cocrystal (DL-1) of DL-Leu and oxalic acid. The crystal structure analysis of DL-1 indicated the occurrence of a
Autor:
Gérard Coquerel, Hirohito Tsue, Sekai Iwama, Hiroki Takahashi, Simon Clevers, Stéphane Veesler, Rui Tamura
Publikováno v:
Crystal Growth & Design
Crystal Growth & Design, American Chemical Society, 2017, 17 (2), pp.671-676. ⟨10.1021/acs.cgd.6b01516⟩
Crystal Growth & Design, 2017, 17 (2), pp.671-676. ⟨10.1021/acs.cgd.6b01516⟩
Crystal Growth & Design, American Chemical Society, 2017, 17 (2), pp.671-676. ⟨10.1021/acs.cgd.6b01516⟩
Crystal Growth & Design, 2017, 17 (2), pp.671-676. ⟨10.1021/acs.cgd.6b01516⟩
A solvent-assisted solid-to-solid polymorphic transition, which was assumed to be one of the key processes for the occurrence of preferential enrichment (PE), has been proven to occur by means of temperature-controlled video-microscopy (TCVM) and tim
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0012c0624e21a55ebace74b2b454dbee
https://hal.archives-ouvertes.fr/hal-01720788
https://hal.archives-ouvertes.fr/hal-01720788
Autor:
Rajesh G. Gonnade, Kenneth D. M. Harris, Hirohito Tsue, Stéphane Veesler, K. Manoj, Rui Tamura, Philip Andrew Williams, Yuko Mori, Hiroki Takahashi, Katsuaki Suzuki, Colan E. Hughes, Sekai Iwama, Kazunori Kuyama
Publikováno v:
Chemistry - A European Journal. 20:10343-10350
An excellent chiral symmetry-breaking spontaneous enantiomeric resolution phenomenon, denoted preferential enrichment, was observed on recrystallization of the 1:1 cocrystal of dl-arginine and fumaric acid, which is classified as a racemic compound c
Publikováno v:
Chemistry-A European Journal
Chemistry-A European Journal, Wiley-VCH Verlag, 2016, 22 (33), pp.11660-11666. ⟨10.1002/chem.201601550⟩
Chemistry-A European Journal, Wiley-VCH Verlag, 2016, 22 (33), pp.11660-11666. ⟨10.1002/chem.201601550⟩
The kinetic/thermodynamic origin of preferential enrichment (PE), which is a spontaneous enantiomeric resolution phenomenon applicable to racemic crystals, is described. The mechanism of PE, which was unveiled with respect to the first-generation of
Publikováno v:
Crystal Growth & Design. 11:607-615
Described is a new strategy using cocrystallization, one of the crystal engineering techniques, to convert a racemic compound crystal into a racemic mixed crystal which can show preferential enrichment, a symmetry-breaking spontaneous enantiomeric re
Autor:
Yoshiaki Uchida, Masahiro Horiguchi, Rui Tamura, Sekai Iwama, Hiroyasu Sato, Hirohito Tsue, Hiroki Takahashi
Publikováno v:
Crystal Growth & Design. 10:2668-2675
The preferential enrichment phenomenon has been observed for two neutral α-amino acids, leucine and alanine, by applying kinetic crystallization conditions using high concentrations and appropriate...
Publikováno v:
Symmetry, Vol 2, Iss 1, Pp 112-135 (2010)
We report the mechanism and scope of “preferential enrichment”, which is an unusual symmetry-breaking enantiomeric resolution phenomenon that is initiated by the solvent-assisted solid-to-solid transformation of a metastable polymorphic form into