Zobrazeno 1 - 10
of 10
pro vyhledávání: '"Sebastian Litters"'
Publikováno v:
Dalton Transactions. 47:2009-2017
Diborane(4) compounds are versatile reagents in synthetic chemistry. Generally, diboranes(4) with sp2-hybridized boron atoms react as electrophiles. By contrast, the chemistry of nucleophilic diborane(4) compounds with two sp3-hybridized boron atoms
Publikováno v:
European Journal of Inorganic Chemistry. 2016:4090-4098
Publikováno v:
Angewandte Chemie. 128:4417-4420
Das rote Tetraboran(4) [B4(hpp)4]3+. (3; hpp=1,3,4,6,7,8-Hexahydro-2H-pyrimido[1,2-a]pyrimidinat) mit einem durch vier N-Donoren stabilisierten rhombischen B4-Gerust entsteht bei der Umsetzung des starken Hydridakzeptors [(Acridin)BCl2][AlCl4] mit de
Publikováno v:
European Journal of Inorganic Chemistry. 2015:5188-5195
Hydride abstraction from the diborane [HB(hpp)]2 (hpp = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidinate) followed by base stabilization led to the first (highly water sensitive) diboranyl phosphonium cations of the general formulas [HB(hpp)2BPR3
Publikováno v:
Angewandte Chemie International Edition. 55:4345-4347
The red-colored tetraborane(4) [B4 (hpp)4 ](3+.) (3; hpp=1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidinate) with a rhomboid B4 skeleton stabilized by four N donors, was synthesized by the reaction of the strong hydride abstraction reagent [(acridi
Publikováno v:
European Journal of Inorganic Chemistry. 2011:2657-2661
The doubly base-stabilized diborane(4) [HB(μ-hpp)]2 (hpp = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidinate) was used as a ligand in the first authenticated example of a dialkylzinc complex and the second example of a zinc halide complex featuri
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 20(39)
Herein, we analyse the catalytic boron-boron dehydrocoupling reaction that leads from the base-stabilised diborane(6) [H2 B(hpp)]2 (hpp=1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidinate) to the base-stabilised diborane(4) [H2 B(hpp)]2 . A number o
Publikováno v:
Nature chemistry. 5(12)
The design of larger architectures from smaller molecular building blocks by element-element coupling reactions is one of the key concerns of synthetic chemistry, so a number of strategies were developed for this bottom-up approach. A general scheme
Autor:
Frank Rominger, Markus Pernpointner, A. Stephen K. Hashmi, Sebastian Litters, Andreas M. Schuster
Publikováno v:
ChemInform. 42
In gold-catalyzed reactions, allenamides mainly afford 1,3-oxazines through atypical 6-exo-dig or 6-endo-dig cyclizations.
Autor:
Markus Pernpointner, A. Stephen K. Hashmi, Frank Rominger, Andreas M. Schuster, Sebastian Litters
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 17(20)
A series of allene amides was prepared and their gold-catalysed cyclisation was investigated. The formation of six-membered rings, 1,3-oxazines, was observed. Dihydropyrroles originating from intramolecular hydroamination of the distal C=C double bon