Zobrazeno 1 - 9
of 9
pro vyhledávání: '"Sebastian Kenzler"'
Autor:
Sebastian Kenzler, Andreas Schnepf
Publikováno v:
Chemical Science
Gold chemistry and the synthesis of colloidal gold have always caught the attention of scientists. While Faraday was investigating the physical properties of colloidal gold in 1857 without probably knowing anything about the exact structure of the mo
Publikováno v:
Dalton Transactions. 49:10765-10771
The reaction of Et3PAuCl with NaBH4 in EtOH leads to the metalloid gold cluster Au32(Et3P)12Cl8 (Au32) or Au54(Et3P)18Cl12 (Au54) depending on the work-up procedure of the reaction mixture. The molecular structure of Au54 is determined by X-ray diffr
Autor:
Nia Pollard, Sebastian Kenzler, Claudio Schrenk, Florian Fetzer, Andreas Schnepf, Andre Clayborne, Andrew R. Frojd
Publikováno v:
Angewandte Chemie International Edition. 58:5902-5905
Three multi-shell metalloid gold clusters of the composition Au32 (R3 P)12 Cl8 (R=Et, n Pr, n Bu) were synthesized in a straightforward fashion by reducing R3 PAuCl with NaBH4 in ethanol. The Au32 core comprises two shells, with the inner one constit
Autor:
Sebastian Kenzler, Andreas Schnepf, Florian Fetzer, Nia Pollard, Andre Clayborne, Claudio Schrenk, Andrew R. Frojd
Publikováno v:
Angewandte Chemie. 131:5962-5966
Autor:
Hannu Häkkinen, Andreas Schnepf, Claudio Schrenk, Sebastian Kenzler, Andrew R. Frojd, Andre Clayborne
Publikováno v:
Chemical Communications. 54:248-251
Reducing (Ph3P)AuSC(SiMe3)3 with L-Selectride® gives the medium-sized metalloid gold cluster Au70S20(PPh3)12. Computational studies show that the phosphine bound Au-atoms not only stabilize the electronic structure of Au70S20(PPh3)12, but also behav
Publikováno v:
Angewandte Chemie International Edition. 56:393-396
The reduction of (Ph3 P)AuCl with NaBH4 in the presence of HSC(SiMe3 )3 , leads to one of the largest metalloid gold clusters: Au108 S24 (PPh3 )16 (1). Within 1 an octahedral Au44 core of gold atoms arranged as in Au metal is surrounded by 48 oxidize
Autor:
Sebastian, Kenzler, Florian, Fetzer, Claudio, Schrenk, Nia, Pollard, Andrew R, Frojd, Andre Z, Clayborne, Andreas, Schnepf
Publikováno v:
Angewandte Chemie (International ed. in English). 58(18)
Three multi-shell metalloid gold clusters of the composition Au
Autor:
Sebastian, Kenzler, Claudio, Schrenk, Andrew R, Frojd, Hannu, Häkkinen, Andre Z, Clayborne, Andreas, Schnepf
Publikováno v:
Chemical communications (Cambridge, England). 54(3)
Reducing (Ph
Publikováno v:
Angewandte Chemie (International ed. in English). 56(1)
The reduction of (Ph