Zobrazeno 1 - 10
of 26
pro vyhledávání: '"Sebastian Heinl"'
Publikováno v:
Chemical Communications. 54:2244-2247
Different reaction pathways were determined between thermolysis and photolysis reactions of the butterfly complex [{CpBIGFe(CO)2}2(μ,η1:1-As4)] (1b). The thermolysis leads to novel arsenic-rich compounds [(CpBIGFe)2(μ,η4:4-As4)] (2b), [(CpBIGFe)3
Autor:
Martin Keilwerth, Julian Müller, Karsten Meyer, Gábor Balázs, Christoph Schwarzmaier, Sebastian Heinl, Manfred Scheer
Publikováno v:
Angewandte Chemie. 129:7418-7423
Das vielfaltige Koordinationsverhalten des P4-Butterfly-Komplexes [{Cp′′′Fe(CO)2}2(μ,η1:1-P4)] (1, Cp′′′=η5-C5H2tBu3) gegenuber Eisen(II)-Verbindungen wird vorgestellt. Die Reaktion von 1 mit [FeBr2⋅dme] ergibt den Chelatkomplex [{Cp
Autor:
Gábor Balázs, Martin Keilwerth, Karsten Meyer, Sebastian Heinl, Julian Müller, Manfred Scheer, Christoph Schwarzmaier
Publikováno v:
Angewandte Chemie International Edition. 56:7312-7317
The versatile coordination behavior of the P4 butterfly complex [{Cp'''Fe(CO)2 }2 (μ,η1:1 -P4 )] (1, Cp'''=η5 -C5 H2t Bu3 ) towards different iron(II) compounds is presented. The reaction of 1 with [FeBr2 ⋅dme] (dme=dimethoxyethane) leads to the
Publikováno v:
Angewandte Chemie. 128:15751-15755
Publikováno v:
Angewandte Chemie International Edition. 55:15524-15527
(Cp2As4)-As-PEt (Cp-PEt = C-5(4-EtC6H4)(5)) (1) is synthesized by the reaction of CpPEtC radicals with yellow arsenic (As-4). In solution an equilibrium of the starting materials and the product is found. However, 1 can be isolated and stored in the
Autor:
Moritz, Modl, Sebastian, Heinl, Gabor, Balázs, Fuencisla, Delgado Calvo, Maria, Caporali, Gabriele, Manca, Martin, Keilwerth, Karsten, Meyer, Maurizio, Peruzzini, Manfred, Scheer
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 25(25)
The reactivity of ruthenium and manganese complexes bearing intact white phosphorus in the coordination sphere was investigated towards the low-valent transition-metal species [Cp'''Co] (Cp'''=η
Publikováno v:
Angewandte Chemie (International Ed. in English)
We report on an effective cluster expansion of CuBr-linked aggregates by the increase of the steric bulk of the Cp(R) ligand in the pentatopic molecules [Cp(R)Fe(η(5)-P5)]. Using [Cp(BIG)Fe(η(5)-P5)] (Cp(BIG)=C5(4-nBuC6H4)5), the novel multishell a
Publikováno v:
Angewandte Chemie. 127:13631-13635
Publikováno v:
Angewandte Chemie. 127:13309-13314
Es wird uber die koordinierenden Eigenschaften neuer Typen zweizahniger Phosphan- und Arsanliganden mit einem engen Bisswinkel berichtet. Die Reaktionen von [{Cp′′′Fe(CO)2}2(μ,η1:1-P4)] (1 a) mit dem Kupfersalz [Cu(CH3CN)4][BF4] fuhrt in Abha
Publikováno v:
Chemical Communications. 51:13474-13477
Thermolysis of [CpMn(η⁶-cht)] with P₄ in 1,3-diisopropylbenzene leads to the formation of the heterocubane [Cp₄Mn₄P₄] (1) in high yields, as a rare example of ‘naked’ phosphorus containing complexes of manganese. Compound 1 is characte