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The importance of lone pairs to structure and bonding of the novel germanium nitridophosphate GeP2N4
Autor:
Tristan de Boer, Cody Somers, Teak Boyko, Sebastian Ambach, Lucien Eisenburger, Wolfgang Schnick, Alexander Moewes
Publikováno v:
Journal of Materials Chemistry A. 11:6198-6204
The new nitridophosphate GeP2N4 differs structurally from all other known MP2N4 phases, owing to a Ge2+ lone pair. Its stereochemical influence could be exploited to tune the properties of other compounds when M2+ is exchanged with Ge2+.