Výsledky vyhledávání - "Sean T, Goralski"

Threefold reactivity of a COF-embedded rhenium catalyst: reductive etherification, oxidative esterification or transfer hydrogenation

Autor: Sean T. Goralski, Krystal M. Cid-Seara, Jenni J. Jarju, Laura Rodriguez-Lorenzo, Alec P. LaGrow, Michael J. Rose, Laura M. Salonen

Publikováno v: Chemical Communications. 58:12074-12077

The reactivity of the novel Re(i) catalyst [Re(C12Anth-py2)(CO)3Br] is modulated by its interactions with the covalent organic framework (COF) TFB-BD.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::26c7fa3413c022312d793838d6f98484
https://doi.org/10.1039/d2cc03173f

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Scaffold-based [Fe]-hydrogenase model: H2 activation initiates Fe(0)-hydride extrusion and non-biomimetic hydride transfer

Autor: Sean T. Goralski, Junhyeok Seo, Vincent M. Lynch, Jason Shearer, Michael J. Rose, Spencer A. Kerns, Eileen R. Sullivan

Publikováno v: Chemical Science. 12:12838-12846

We report the synthesis and reactivity of a model of [Fe]-hydrogenase derived from an anthracene-based scaffold that includes the endogenous, organometallic acyl(methylene) donor. In comparison to other non-scaffolded acyl-containing complexes, the c

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3f0e3cd88cf6e99c54dbd24d8b219db0
https://doi.org/10.1039/d0sc03154b

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Modulating extraction and retention of fluorinated β-diketonate metal complexes in perfluorocarbons through the use of non-fluorinated neutral ligands

Autor: Sean T. Goralski, Dawson A. Grimes, Richard A. Jones, Emily L. Que, Orhi Esarte Palomero, Tyler L. King

Publikováno v: Inorganic Chemistry Frontiers. 8:4488-4496

Extraction of metal ions into perfluorocarbon solvents using fluorinated ligands has shown promise in a number of applications ranging from catalysis to biomedical imaging. However, the speciation of the extracted metal complexes is poorly understood

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3b7d4747253f6c0319b239f1a371c803
https://doi.org/10.1039/d1qi00817j

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Divergent Solution and Solid-State Structures of Mono- and Dinuclear Nickel(II) Pyridone Complexes

Autor: Michael J. Rose, Simone E. A. Lumsden, Vincent M. Lynch, Sean T. Goralski, Taylor A. Manes

Publikováno v: Organometallics. 39:1070-1079

The chelating 2-pyridone ligand (E)-6-(1-((2-(methylthio)phenyl)imino)ethyl)pyridin-2(1H)-one (1) has been used to synthesize five nickel(II) complexes that have been characterized by single-crysta...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::6050d74f51cb4663bb26e9d279042d17
https://doi.org/10.1021/acs.organomet.9b00799

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Emerging artificial metalloenzymes for asymmetric hydrogenation reactions

Autor: Sean T. Goralski, Michael J. Rose

Publikováno v: Current opinion in chemical biology. 66

Artificial metalloenzymes (ArMs) utilize the best properties of homogenous transition metal catalysts and naturally occurring proteins. While synthetic metal complexes offer high tunability and broad-scope reactivity with a variety of substrates, enz

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::469eee271f15dbd09a8daa8238002ed7
https://pubmed.ncbi.nlm.nih.gov/34879303

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Scaffold-based [Fe]-hydrogenase model: H

Autor: Spencer A, Kerns, Junhyeok, Seo, Vincent M, Lynch, Jason, Shearer, Sean T, Goralski, Eileen R, Sullivan, Michael J, Rose

Publikováno v: Chemical Science

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::bfa4fb0362a3d371f407424cf70dc371
https://pubmed.ncbi.nlm.nih.gov/34703571

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