Zobrazeno 1 - 10
of 11
pro vyhledávání: '"Sean P. Vilanova"'
Autor:
Iker del Rosal, Justin R. Walensky, Steven P. Kelley, Sean P. Vilanova, Laurent Maron, Michael L. Tarlton
Publikováno v:
Organometallics. 39:2152-2161
A study of the comparative reactivity of CO, CO2, tBuCN, and tBuNC with (C5Me5)2An[P(H)Mes]2 (An = Th, U) has been undertaken. While CO2 and tBuNC form identical products with both metals, namely (...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ae400532bff03e8dd1426c52c8788897
https://doi.org/10.1021/acs.organomet.0c00221
https://doi.org/10.1021/acs.organomet.0c00221
Autor:
Justin R. Walensky, Sean P. Vilanova, Steven P. Kelley, Michael L. Tarlton, M. Gayanethra Kaumini, Patrick Huang
Publikováno v:
Inorganic chemistry. 60(19)
To synthesize complexes with thorium-phosphorus multiple-bond character, reactions of (C5Me5)2Th[P(H)Mes]2 with monovalent alkali-metal bases, MN(SiMe3)2, as well as CuMes, have been investigated. The results with MN(SiMe3)2 are phosphinidiide comple
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fa2e910135647989e79ae5f5cb436285
https://pubmed.ncbi.nlm.nih.gov/34528785
https://pubmed.ncbi.nlm.nih.gov/34528785
Autor:
Pokpong Rungthanaphatsophon, Jochen Autschbach, Charles L. Barnes, Justin R. Walensky, Enrique R. Batista, Sean P. Vilanova, Thomas J. Duignan, Alexander J. Myers, Ping Yang
Publikováno v:
Inorganic Chemistry. 57:7270-7278
A series of metallocene thorium complexes with mono- and bis(phosphido) ligands have been investigated with varying hues: (C5Me5)2Th(Cl)[P(Mes)2] (Mes = mesityl = 2,4,6-(CH3)3C6H2; dark red-purple), (C5Me5)2Th[P(Mes)(CH3)]2 (dark red-purple), (C5Me5)
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9a089916c02335bb3f2fabba6f3ad311
https://doi.org/10.1021/acs.inorgchem.8b00922
https://doi.org/10.1021/acs.inorgchem.8b00922
Publikováno v:
Journal of Organometallic Chemistry. 857:159-163
The reactivity of thorium-phosphorus bonds was investigated with benzophenone. The insertion of two equivalents of benzophenone into both thorium-phosphorus bonds in (C5Me5)2Th[PH(2,4,6-R3C6H2)]2, R = Me or iPr, was observed. In addition, a new thori
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::90a6178c63fdbfc9ad4ed63ed64841ac
https://doi.org/10.1016/j.jorganchem.2017.10.023
https://doi.org/10.1016/j.jorganchem.2017.10.023
Autor:
Sean P. Vilanova, Wayne W. Lukens, Andrew C. Behrle, Justin R. Walensky, Stephen P Kelley, Pokpong Rungthanaphatsophon, Alexander J. Myers
Publikováno v:
Chemical Communications. 54:10435-10438
The synthesis and characterization of U(iv) and Np(iv) selenium bis(phenolate) complexes are reported. The reaction of two equivalents of the U(iv) complex with p-benzoquinone results in the formation of a U(v)-U(v) species with a bridging reduced qu
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f756babe48682d349177426f1a147c67
https://doi.org/10.1039/c8cc05244a
https://doi.org/10.1039/c8cc05244a
Autor:
Robert J. Ward, Iker del Rosal, Sean P. Vilanova, Justin R. Walensky, Steven P. Kelley, Laurent Maron, Pokpong Rungthanaphatsophon
Publikováno v:
Organometallics
Organometallics, 2019, 38 (8), pp.1733-1740. ⟨10.1021/acs.organomet.9b00043⟩
Organometallics, 2019, 38 (8), pp.1733-1740. ⟨10.1021/acs.organomet.9b00043⟩
International audience; To probe the reactivity of two potential sites at tetravalent thorium and uranium metal centers, we examined the monophosphido methyl complexes, (C5Me5)(2)An(CH3)[P(SiMe3)(Mes)], An = Th, U; Mes = 2,4,6-Me3C6H2. Reaction of th
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::934a3fbe5e81f1415b2656938428ceba
https://hal.insa-toulouse.fr/hal-04022184
https://hal.insa-toulouse.fr/hal-04022184
Autor:
Sean P. Vilanova, Vlad M. Iluc
Publikováno v:
Organometallics. 35:2110-2123
The synthesis of the N-aryl-substituted PNP pro-ligands H(PNnaphP) (N-di(2-diisopropylphosphine-4-methylphenyl)naphthylamine) and H(PNtolP) (N-di(2-diisopropylphosphine-4-methylphenyl)-o-tolylamine) is reported. The corresponding iridium(III) complex
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3eaf3be7187a569e4f5d6b7a2509555d
https://doi.org/10.1021/acs.organomet.6b00333
https://doi.org/10.1021/acs.organomet.6b00333
Autor:
Sean P. Vilanova, Justin R. Walensky
Publikováno v:
Encyclopedia of Inorganic and Bioinorganic Chemistry
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::05493f7788b4f04e2bfc673a4d767f45
https://doi.org/10.1002/9781119951438.eibc2551
https://doi.org/10.1002/9781119951438.eibc2551
Publikováno v:
Angewandte Chemie International Edition
Angewandte Chemie International Edition, 2018, 57 (51), pp.16748-16753. ⟨10.1002/anie.201810511⟩
Angewandte Chemie International Edition, 2018, 57 (51), pp.16748-16753. ⟨10.1002/anie.201810511⟩
International audience; We report intramolecular proton transfer reactions to functionalize carbon monoxide and tert-butyl nitrile from a bis(phosphido) thorium complex. The reaction of (C5Me5)(2)Th[PH(Mes)](2), Mes = 2,4,6-Me3C6H2, with 1 atm of CO
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3a58cb40c51ce9d08190af9133b164b4
https://pubmed.ncbi.nlm.nih.gov/30329202
https://pubmed.ncbi.nlm.nih.gov/30329202
Autor:
Alexander J, Myers, Pokpong, Rungthanaphatsophon, Andrew C, Behrle, Sean P, Vilanova, Stephen P, Kelley, Wayne W, Lukens, Justin R, Walensky
Publikováno v:
Chemical communications (Cambridge, England). 54(74)
The synthesis and characterization of U(iv) and Np(iv) selenium bis(phenolate) complexes are reported. The reaction of two equivalents of the U(iv) complex with p-benzoquinone results in the formation of a U(v)-U(v) species with a bridging reduced qu
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::dac9f34302227c254e08c1155537d11d
https://pubmed.ncbi.nlm.nih.gov/30167613
https://pubmed.ncbi.nlm.nih.gov/30167613