Zobrazeno 1 - 8
of 8
pro vyhledávání: '"Sean O. Wilson"'
Publikováno v:
The Journal of Organic Chemistry. 82:6738-6747
1,3-Disiloxanediols are effective hydrogen-bonding catalysts that exhibit enhanced activity relative to silanediols and triarylsilanols. The catalytic activity for a series of 1,3-disiloxanediols, including naphthyl-substituted and unsymmetrical silo
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e596848e1da58bde3783838af46f8469
https://doi.org/10.1021/acs.joc.7b00875
https://doi.org/10.1021/acs.joc.7b00875
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 22(51)
A series of new 1,3-disiloxanediols has been synthesized, including naphthyl-substituted and unsymmetrical siloxanes, and demonstrated as a new class of anion-binding catalysts. In the absence of anions, diffusion-ordered spectroscopy (DOSY) displays
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8d1b54d11c3005e1047a2a7b49e3268c
https://pubmed.ncbi.nlm.nih.gov/27862424
https://pubmed.ncbi.nlm.nih.gov/27862424
Autor:
Annaliese K. Franz, Sean O. Wilson
Publikováno v:
Journal of Medicinal Chemistry. 56:388-405
The incorporation of silicon and synthesis of organosilicon small molecules provide unique opportunities for medicinal applications. The biological investigation of organosilicon small molecules is particularly interesting because of differences in t
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c8ed0c92883ec5f4972e47d69f7393a3
https://doi.org/10.1021/jm3010114
https://doi.org/10.1021/jm3010114
Publikováno v:
Organometallics. 31:6715-6718
The synthesis, isolation, and hydrogen-bonding properties of a series of amide-containing silanediols are described, including an enantioenriched silanediol. By incorporation of a 2,4,6-trimethylphenyl (mesityl) group, these functionalized silanediol
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e56f26525fcc1a92d6c0adc664509a3e
https://doi.org/10.1021/om300736n
https://doi.org/10.1021/om300736n
Publikováno v:
Organic Letters. 14:186-189
The importance of cooperative hydrogen-bonding effects and SiOH-acidification is described for silanediol catalysis. NMR binding, X-ray, and computational studies provide support for a unique dimer resulting from silanediol self-recognition. The sign
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3e2adcd72dda5638c538f0f21f303265
https://doi.org/10.1021/ol202971m
https://doi.org/10.1021/ol202971m
Publikováno v:
Chem. Commun.. 50:3738-3740
X-ray crystallography showcases the distinct self-association and hydrogen-bonding patterns of organic silanediols, R2Si(OH)2, with bifunctional heterocycles for supramolecular assembly. Diffusion-ordered spectroscopy (DOSY) studies identify the domi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::041a8cd0c0ac9d50753cea766659fe63
https://doi.org/10.1039/c4cc00672k
https://doi.org/10.1039/c4cc00672k
Publikováno v:
ChemInform. 44
We report the Lewis acid catalyzed additions of allylsilanes to N-Boc-iminooxindoles and the formation of novel silicon-containing spirocarbamates via intramolecular trapping of a β-silyl carbocation by an N-Boc group. Several transformations displa
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ed8ef675565fb91d7ea00e8aa95720b8
https://doi.org/10.1002/chin.201348119
https://doi.org/10.1002/chin.201348119
Publikováno v:
Organic letters. 15(13)
We report the Lewis acid catalyzed additions of allylsilanes to N-Boc-iminooxindoles and the formation of novel silicon-containing spirocarbamates via intramolecular trapping of a β-silyl carbocation by an N-Boc group. Several transformations displa
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8f3add1c118c61f6f164a5f17bb47ba0
https://pubmed.ncbi.nlm.nih.gov/23758331
https://pubmed.ncbi.nlm.nih.gov/23758331