Promoting oxo functionalization in the uranyl ion by ligation to ketimides

Autor: Seaman, Lani A., Pedrick, Elizabeth A., Wu, Guang, Hayton, Trevor W.

Publikováno v: In Journal of Organometallic Chemistry 15 February 2018 857:34-37

Synthesis, Characterization, and Electrochemistry of the Homoleptic f Element Ketimide Complexes [Li]2[M(N═CtBuPh)6] (M = Ce, Th)

Autor: Assefa, Mikiyas K, Sergentu, Dumitru-Claudiu, Seaman, Lani A, Wu, Guang, Autschbach, Jochen, Hayton, Trevor W

Publikováno v: Inorganic chemistry, vol 58, iss 19

Reaction of [Ce(NO3)3(THF)4] with 6 equiv of Li(N═CtBuPh), followed by addition of 0.5 equiv of I2, affords the homoleptic Ce(IV) ketimide [Li]2[Ce(N═CtBuPh)6] (1), which can be isolated in 44% yield after workup. Similarly, reaction of [ThCl4(DM

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Comparison of the Reactivity of 2-Li-C6H4CH2NMe2 with MCl4 (M=Th, U): Isolation of a Thorium Aryl Complex or a Uranium Benzyne Complex.

Autor: Seaman, Lani A.¹, Pedrick, Elizabeth A.¹, Tsuchiya, Takashi², Wu, Guang¹, Jakubikova, Elena² ejakubi@ncsu.edu, Hayton, Trevor W.¹ hayton@chem.ucsb.edu

Publikováno v: Angewandte Chemie. Sep2013, Vol. 125 Issue 40, p10783-10786. 4p.

Synthesis, structure and bonding of hexaphenyl thorium(IV): Observation of a non-octahedral structure

Autor: Pedrick, Elizabeth A, Hrobárik, Peter, Seaman, Lani A, Wu, Guang, Hayton, Trevor W

Publikováno v: Pedrick, EA; Hrobárik, P; Seaman, LA; Wu, G; & Hayton, TW. (2016). Synthesis, structure and bonding of hexaphenyl thorium(IV): Observation of a non-octahedral structure. Chemical Communications, 52(4), 689-692. doi: 10.1039/c5cc08265j. UC Santa Barbara: Retrieved from: http://www.escholarship.org/uc/item/9j38q9ph
Chemical communications (Cambridge, England), vol 52, iss 4

Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich. This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national

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