Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Scott D. Woodgate"'
Publikováno v:
Acta Crystallographica Section E, Vol 65, Iss 11, Pp m1319-m1319 (2009)
The crystal structure of the title compound, [Os(C6H7S)Cl(C18H15P)2(CO)], confirms the formulation as an osmabenzene. There is a slightly distorted octahedral coordination environment at the OsII ion, with the triphenylphosphane ligands mutually tran
Externí odkaz:
https://doaj.org/article/86158ae323fb400bb0899e2ac3e81bad
Publikováno v:
Organometallics. 29:5358-5365
The purple osmabenzene complex Os(C5H4{SMe-1})(CF3SO3)(CO)(PPh3)2 (1) is formed in high yield through reaction between Os(C5H4{S-1})(CO)(PPh3)2 and methyl triflate. The neutral blue osmabenzenes Os(C5H4{SMe-1})(cis-X)(CO)(PPh3)2 (X = I (2a), Cl (2b),
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2df18a0a40d237d1599124c4bf2f0b49
https://doi.org/10.1021/om1003754
https://doi.org/10.1021/om1003754
Publikováno v:
Journal of Organometallic Chemistry. :168-173
Reaction between OsHCl(CO)(PPh3)3 and the powerful π-accepting ligand tris(N-pyrrolyl)phosphine, P(NC4H4)3, results in replacement of the PPh3 ligand trans to hydride giving OsHCl(CO)[P(NC4H4)3](PPh3)2 (1). The analogue of 1 with Cl replaced by p-to
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::95800e1f0c446a0eb200b8eaa93b27bd
https://doi.org/10.1016/s0022-328x(01)01383-3
https://doi.org/10.1016/s0022-328x(01)01383-3
Autor:
Alex Williamson, Warren R. Roper, Scott D. Woodgate, L. James Wright, Clifton E. F. Rickard, Markus Albrecht
Publikováno v:
Journal of Organometallic Chemistry. 625:77-85
Reaction between OsPhCl(CO)(PPh 3 ) 2 and HSi(OEt) 3 gives the five-coordinate complex, Os[Si(OEt) 3 ]Cl(CO)(PPh 3 ) 2 ( 1 ), the crystal structure of which reveals a square pyramidal geometry with the triethoxysilyl ligand at the apical site and the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b62e30ecd062aac1bee543bd10a058c7
https://doi.org/10.1016/s0022-328x(00)00899-8
https://doi.org/10.1016/s0022-328x(00)00899-8
Publikováno v:
Journal of Organometallic Chemistry. 623:109-115
Reaction between Os(CS)(CO)(PPh 3 ) 3 and propyne gives a complex mixture of products from which can be isolated the simple oxidative addition product Os(CCMe)H(CS)(CO)(PPh 3 ) 2 ( 1 ) and the osmabenzene Os(η 2 -C[S]CMeCHCHC Me)(CO)(PPh 3 ) 2 (
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::441651f3af186617877a931c518f638f
https://doi.org/10.1016/s0022-328x(00)00717-8
https://doi.org/10.1016/s0022-328x(00)00717-8
Publikováno v:
Journal of Organometallic Chemistry. 619:293-298
A convenient preparation of Hg[C6H4(CH2OH)-2]Cl (1) involves treatment of dilithiated benzyl alcohol with HgCl2. 1 is smoothly oxidised to Hg[C6H4(CHO)-2]Cl (2) by reaction with pyridinium chlorochromate (PCC). The crystal structure of 2 reveals a tw
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::fc1f65e2b8d5f9306c4515c716494e85
https://doi.org/10.1016/s0022-328x(00)00699-9
https://doi.org/10.1016/s0022-328x(00)00699-9
Publikováno v:
Journal of Organometallic Chemistry. 609:177-183
Reaction between Os(CO) 2 (PPh 3 ) 3 and the silatrane, HSi{OCH 2 CH 2 } 3 N, gives the osmium(II) silatranyl, hydride complex Os(Si{OCH 2 CH 2 } 3 N)H(CO) 2 (PPh 3 ) 2 ( 1 ), as a mixture of three isomers, the structures of which were determined by
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::91d5cf896f98360986e31b1ab80e06e7
https://doi.org/10.1016/s0022-328x(00)00110-8
https://doi.org/10.1016/s0022-328x(00)00110-8
Publikováno v:
Journal of Organometallic Chemistry. 607:27-40
Reaction between MHCl(CO)(PPh3)3 (M=Ru, Os) and the o-halophenyl mercury compounds, Hg(C6H4X-2)2 (X=Cl, Br, I) gives the five co-ordinate complexes, M(C6H4X-2)Cl(CO)(PPh3)2 (1a M=Ru, X=Cl; 1b M=Ru, X=Br; 2a M=Os, X=Cl; 2b M=Os, X=Br; 2c M=Os, X=I). I
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::37cffae48766403732efd7b70083ea29
https://doi.org/10.1016/s0022-328x(00)00170-4
https://doi.org/10.1016/s0022-328x(00)00170-4
Publikováno v:
Journal of Organometallic Chemistry. 565:153-158
When treated with lithium triethylborohydride, the cationic carbyne complexes [Os(–CR)(CO)2(PPh3)2]+(R=1-naphthyl, 1; R=2-naphthyl, 2) form 3 and 4, respectively, which both have the formula Os(C11H8)(CO)2(PPh3)2. NMR studies of these two isomeric
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a9152920493e30aeadc20c2f740a1a9f
https://doi.org/10.1016/s0022-328x(98)00451-3
https://doi.org/10.1016/s0022-328x(98)00451-3
Autor:
L. James Wright, George R. Clark, Clifton E. F. Rickard, Warren R. Roper, Scott D. Woodgate, L.-J. Baker
Publikováno v:
Journal of Organometallic Chemistry. 551:247-259
Treatment of the dichlorocarbene-containing complex, Os(CCl2)Cl2(CO)(PPh3)2 with two equivalents of 1-naphthyllithium or two equivalents of 2-naphthyllithium in the presence of N,N,N′,N′-tetramethylethylenediamine (tmeda) gives the correspondi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f8ac73487232ca464975184ffa13d74f
https://doi.org/10.1016/s0022-328x(97)00440-3
https://doi.org/10.1016/s0022-328x(97)00440-3